Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes | |
Department | 固体润滑国家重点实验室 |
Jiao TF(焦体峰); Yang N(杨娜); Zhou JX(周靖欣) | |
2011 | |
Source Publication | Materials Science Forum |
ISSN | 1662-9752 |
Volume | 694Pages:667-671 |
Abstract | Some Schiff base compounds with aromatic substituted groups and their Cu-complexes have been designed and synthesized from the reaction of aromatic amines with salicylaldehyde. It has been found that depending on the molecular structures and substituted groups, the formed Schiff base compounds showed different properties, indicating distinct regulation of molecular design. UV and IR data confirmed commonly the formation of Schiff base and coordination with Cu(II) ions, as well as aromatic segment in molecular structures. In addition, the process of ex situ coordination seemed to change differently along with adding time, which could be ascribable to the presence of distinct substituted group and change of reaction activity. The spectral difference is mainly attributed to molecular structures, formation of Schiff base group and different substituted groups. The present results have showed that the special properties of Schiff base compounds could be turned by modifying molecular structures and substituted groups, which show potential application in fields of functional material fields such as liquid crystal and catalysts. |
Keyword | Schiff Base Metal Complex Liquid Crystal Spectral Measurement |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Doctoral Foundation of Yanshan University (NO.B360) |
Indexed By | SCI |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/793 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Jiao TF(焦体峰) |
Recommended Citation GB/T 7714 | Jiao TF,Yang N,Zhou JX. Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes[J]. Materials Science Forum,2011,694:667-671. |
APA | 焦体峰,杨娜,&周靖欣.(2011).Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes.Materials Science Forum,694,667-671. |
MLA | 焦体峰,et al."Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes".Materials Science Forum 694(2011):667-671. |
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