Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface | |
Department | 固体润滑国家重点实验室 |
Jiao TF(焦体峰); Zhou JX(周靖欣) | |
2011 | |
Source Publication | Materials Science Forum
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ISSN | 1662-9752 |
Volume | 694Pages:778-782 |
Abstract | Great interest has been given to the Schiff base amphiphiles with special molecular structures because of their unique properties. In this article, we report some interesting properties of the interfacial films formed by a newly designed trigonal amphiphiles Schiff base containing hydrophobic core and aromatic periphery. This novel Schiff base amphiphile could be spread to form stable monolayers and coordinated with Cu(Ac)2 in situ in the monolayer. The coordination with Cu(II) ion has a great effect on the regulation of the properties of the Langmuir monolayers. A larger limiting molecular area was observed for the monolayers of the trigonal amphiphile on Cu(II) ions subphase. Both the monolayers on water and on the aqueous Cu(Ac)2 subphase were transferred onto solid substrates, and different morphologies were observed for films. The present work provided new insight into the design and interfacial assembly of novel Schiff base amphiphiles with special molecular structures and substituted groups. |
Keyword | Trigonal Schiff Base Interfacial Coordination Hydrophobic Core Aromatic Periphery Lb Film Spectral Measurement |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Doctoral Foundation of Yanshan University (NO.B360) |
Indexed By | SCI |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/792 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Jiao TF(焦体峰) |
Recommended Citation GB/T 7714 | Jiao TF,Zhou JX. Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface[J]. Materials Science Forum,2011,694:778-782. |
APA | 焦体峰,&周靖欣.(2011).Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface.Materials Science Forum,694,778-782. |
MLA | 焦体峰,et al."Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface".Materials Science Forum 694(2011):778-782. |
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