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Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface
Department固体润滑国家重点实验室
Jiao TF(焦体峰); Zhou JX(周靖欣)
2011
Source PublicationMaterials Science Forum
ISSN1662-9752
Volume694Pages:778-782
AbstractGreat interest has been given to the Schiff base amphiphiles with special molecular structures because of their unique properties. In this article, we report some interesting properties of the interfacial films formed by a newly designed trigonal amphiphiles Schiff base containing hydrophobic core and aromatic periphery. This novel Schiff base amphiphile could be spread to form stable monolayers and coordinated with Cu(Ac)2 in situ in the monolayer. The coordination with Cu(II) ion has a great effect on the regulation of the properties of the Langmuir monolayers. A larger limiting molecular area was observed for the monolayers of the trigonal amphiphile on Cu(II) ions subphase. Both the monolayers on water and on the aqueous Cu(Ac)2 subphase were transferred onto solid substrates, and different morphologies were observed for films. The present work provided new insight into the design and interfacial assembly of novel Schiff base amphiphiles with special molecular structures and substituted groups.
KeywordTrigonal Schiff Base Interfacial Coordination Hydrophobic Core Aromatic Periphery Lb Film Spectral Measurement
Subject Area材料科学与物理化学
Funding Organizationthe National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (Lanzhou Institute of Chemical Physics;CAS) (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Doctoral Foundation of Yanshan University (NO.B360)
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/792
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorJiao TF(焦体峰)
Recommended Citation
GB/T 7714
Jiao TF,Zhou JX. Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface[J]. Materials Science Forum,2011,694:778-782.
APA 焦体峰,&周靖欣.(2011).Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface.Materials Science Forum,694,778-782.
MLA 焦体峰,et al."Research on interfacial coordination of trigonal Schiff base compound with hydrophobic core and aromatic periphery at air/water interface".Materials Science Forum 694(2011):778-782.
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