Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes | |
Department | OSSO国家重点实验室 |
Zhang CY(张春艳)1,2; Liu JH(刘建华)1; Xia CG(夏春谷)1; Liu JH(刘建华); Xia CG(夏春谷) | |
2014 | |
Source Publication | Organic & Biomolecular Chemistry |
ISSN | 1477-0520 |
Volume | 12Issue:47Pages:9702-9706 |
Abstract | A series of aryl-palladium-NHC compounds was prepared according to the reported methods and their catalytic activity in the carbonylation of aryl iodides to synthesize alpha-keto amides and alkynones was examined. These practical aryl-palladium-NHC complexes have shown highly efficient catalyzed carbonylation and Sonogashira carbonylation reactions, with high turnover number in synthesis of alpha-keto amides (TON = 4300) and in synthesis of alkynones (TON = 980). |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c4ob01878h |
Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21373248;21133011;21073209) |
Indexed By | SCI |
If | 3.562 |
Language | 英语 |
Funding Project | 均相催化课题组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/6814 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Liu JH(刘建华); Xia CG(夏春谷) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
Recommended Citation GB/T 7714 | Zhang CY,Liu JH,Xia CG,et al. Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes[J]. Organic & Biomolecular Chemistry,2014,12(47):9702-9706. |
APA | Zhang CY,Liu JH,Xia CG,刘建华,&夏春谷.(2014).Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes.Organic & Biomolecular Chemistry,12(47),9702-9706. |
MLA | Zhang CY,et al."Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes".Organic & Biomolecular Chemistry 12.47(2014):9702-9706. |
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Aryl-palladium-NHC c(237KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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