| 2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization | |
| Department | 羰基合成与选择氧化国家重点实验室 |
| Liu H(刘浩); Zhao WZ(赵炜珍); Hao X(郝项); Carl Redshaw; Huang W(黄伟); Sun WH(孙文华) | |
| 2011 | |
| Source Publication | Organometallics
 |
| ISSN | 0276-7333 |
| Volume | 30Pages:2418-2424 |
| Abstract | A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines (L1 L5) and the nickel(II) dibromide complexes thereof (C1 C5) were synthesized and fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) procatalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 107 g of PE (mol of Ni) 1 h 1. |
| Subject Area | 物理化学 |
| Funding Organization | the MOST 863 program No. 2009AA033601;C.R. thanks the EPSRC for an overseas travel grant (No. EP/H031855/1) |
| Indexed By | SCI |
| Language | 英语 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/405 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun WH(孙文华) |
| Recommended Citation GB/T 7714 | Liu H,Zhao WZ,Hao X,et al. 2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization[J]. Organometallics,2011,30:2418-2424. |
| APA | 刘浩,赵炜珍,郝项,Carl Redshaw,黄伟,&孙文华.(2011).2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization.Organometallics,30,2418-2424. |
| MLA | 刘浩,et al."2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization".Organometallics 30(2011):2418-2424. |
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