| A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc | |
| Department | OSSO国家重点实验室 |
Gao G(高广)1; Bai XF(柏惺峰)1; Li F(李菲)1; Zheng LS(郑龙生)1; Zheng ZJ(郑战江)1; Lai GQ(来国桥)1; Jiang KZ(蒋可志)1; Li FW(李福伟)2 ; Xu LW(徐利文)1; Xu LW(徐利文)
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| 2012 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 0040-4039 |
| Volume | 53Issue:17Pages:2164-2166 |
| Abstract | We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)4 or other Lewis acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good yields. |
| Keyword | Organosilicon Chemistry Reduction Diethylzinc Silane Lewis Acid |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.tetlet.2012.02.059 |
| Funding Organization | the National Natural Science Founder of China (No. 20973051;21173064);Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT);Zhejiang Provincial Natural Science Foundation of China (Y4090139) |
| Indexed By | SCI |
| If | 2.397 |
| Language | 英语 |
| Funding Project | 均相催化研究组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3881 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Gao G,Bai XF,Li F,et al. A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc[J]. Tetrahedron Letters,2012,53(17):2164-2166. |
| APA | Gao G.,Bai XF.,Li F.,Zheng LS.,Zheng ZJ.,...&徐利文.(2012).A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc.Tetrahedron Letters,53(17),2164-2166. |
| MLA | Gao G,et al."A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc".Tetrahedron Letters 53.17(2012):2164-2166. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B38.Tetrahedron Lett（272KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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