| Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant | |
| Department | OSSO国家重点实验室 |
Xu DQ(徐大乾)1,2; Wang SF(王寿峰)1 ; Shen ZQ(沈志强)1; Xia CG(夏春谷)1; Sun W(孙伟)1; Sun W(孙伟)
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| 2012 | |
| Source Publication | Organic and Biomolecular Chemistry
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| ISSN | 1477-0520 |
| Volume | 10Issue:14Pages:2730-2732 |
| Abstract | We demonstrate an efficient enantioselective oxidation of secondary alcohols catalyzed by Mn(III)-salen complex using N-bromosuccinimide (NBS) as the oxidant. The new protocol is very efficient for the oxidative kinetic resolution of a variety of secondary alcohols, including ortho-substituted benzylic alcohols. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c2ob07087a |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (20873166;21073210;21133011) |
| Indexed By | SCI |
| If | 3.568 |
| Language | 英语 |
| Funding Project | 生物与仿生催化课题组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3855 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Sun W(孙伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Xu DQ,Wang SF,Shen ZQ,et al. Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant[J]. Organic and Biomolecular Chemistry,2012,10(14):2730-2732. |
| APA | Xu DQ,Wang SF,Shen ZQ,Xia CG,Sun W,&孙伟.(2012).Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant.Organic and Biomolecular Chemistry,10(14),2730-2732. |
| MLA | Xu DQ,et al."Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes with N-bromosuccinimide as a powerful oxidant".Organic and Biomolecular Chemistry 10.14(2012):2730-2732. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| B12.Org. Biomol. Che（117KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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