| Tandem Oxidative Dearomatization/Intramolecular Diels-Alder Reaction for Construction of the Tricyclic Core of Palhinine A | |
| Department | OSSO国家重点实验室 |
| Zhao CG(赵常贵)1; Zheng HJ(郑怀基)1; Jing P(靖鹏)1; Fang BW(方博文)1; Xie XG(谢新刚)1; She XG(厍学功)1,2; Xie XG(谢新刚); She XG(厍学功) | |
| 2012 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 14Issue:9Pages:2293-2295 |
| Abstract | A concise construction of the 6/6/5 tricyclic core of Lycopodium alkaloid palhinine A (1) has been accomplished. The developed synthetic strategy featured a tandem oxidative dearomatization/intramolecular Diels-Alder reaction to construct C/D rings and an intramolecular 5-exo-trig radical cyclization to install the B ring of palhinine A (1). The developed approach paves the way for the total synthesis of palhinine A (1). |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/ol3007138 |
| Funding Organization | the MOST (2010CB833200);the NSFC(21125207;21072086;21102062);program 111 |
| Indexed By | SCI |
| If | 6.142 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3824 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xie XG(谢新刚); She XG(厍学功) |
| Affiliation | 1.Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao CG,Zheng HJ,Jing P,et al. Tandem Oxidative Dearomatization/Intramolecular Diels-Alder Reaction for Construction of the Tricyclic Core of Palhinine A[J]. Organic Letters,2012,14(9):2293-2295. |
| APA | Zhao CG.,Zheng HJ.,Jing P.,Fang BW.,Xie XG.,...&厍学功.(2012).Tandem Oxidative Dearomatization/Intramolecular Diels-Alder Reaction for Construction of the Tricyclic Core of Palhinine A.Organic Letters,14(9),2293-2295. |
| MLA | Zhao CG,et al."Tandem Oxidative Dearomatization/Intramolecular Diels-Alder Reaction for Construction of the Tricyclic Core of Palhinine A".Organic Letters 14.9(2012):2293-2295. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 43.Org. Lett.,2012,1（297KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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