| Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride | |
| Department | 绿色化学与催化研发中心 |
Duan ZY(段志英); Gu YL(顾彦龙); Deng YQ(邓友全)
| |
| 2006 | |
| Source Publication | Journal of Molecular Catalysis A: Chemical
 |
| ISSN | 1381-1169 |
| Volume | 246Pages:70-75 |
| Abstract | Esterification of tert-butanol by acetic anhydride, a typical acid–base catalytic reaction, was conducted with excellent selectivity and high yield in a neutral ionic liquid [BMIm]BF4 (1-butyl-3-methylimidazolium tetrafluoroborate). Many other tertiary alcohols could also be successfully converted to the corresponding esters in [BMIm]BF4. Separation of product and recovery and reuse of ionic liquid are all convenient in this system. Here, the need for catalysts is avoided through the use of catalytically active ionic liquids as solvents. |
| Keyword | [Bmim]Bf4 Esterification Tertiary Alcohol Acetic Anhydride |
| Subject Area | 物理化学 |
| Funding Organization | National Natural Science Foundation of China (No. 20225309;20533080) |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/3666 |
| Collection | 绿色化学研究发展中心 |
| Corresponding Author | Deng YQ(邓友全) |
| Recommended Citation GB/T 7714 | Duan ZY,Gu YL,Deng YQ. Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride[J]. Journal of Molecular Catalysis A: Chemical,2006,246:70-75. |
| APA | 段志英,顾彦龙,&邓友全.(2006).Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride.Journal of Molecular Catalysis A: Chemical,246,70-75. |
| MLA | 段志英,et al."Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride".Journal of Molecular Catalysis A: Chemical 246(2006):70-75. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 段志英-JMC-A.pdf（137KB） | 开放获取 | License | View Application Full Text | |||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment