Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints | |
Department | 环境材料与生态化学研究发展中心 |
Geng QF(耿庆芬)2,3; Zhao X(赵鑫)1; Gao XH(高祥虎)1; Yang SR(杨生荣)2; Liu G(刘刚)1; Liu G(刘刚) | |
The second department | 固体润滑国家重点实验室 |
2012 | |
Source Publication | Journal of Sol-Gel Science and Technology |
ISSN | 0928-0707 |
Volume | 61Issue:1Pages:281-288 |
Abstract | CuCr2O4 spinel powder with high quality black hue, investigated as solar-absorbing pigment for spectrally selective paint, was synthesized by an environmental friendly sol-gel combustion process using citric acid as the fuel and metal nitrates as oxidizers. Single-phase CuCr2O4 spinel crystals were obtained after heat treatment of the as burnt powder at a low temperature (600 C) and the average crystallite size of the CuCr2O4 powders increased with the calcining temperature. Morphological analysis of powders calcined at various temperatures was done by field emission scanning electron microscopy. CuCr2O4 powder calcined at 700 C was chosen as pigment to fabricate thickness sensitive spectrally selective paint coatings by simple spray-coating technique. For the sake of comparison, the as-burnt powder composed of mixed metal oxides (i.e., CuO and Cr2O3) was also used as pigment. The results reveal that the spinel CuCr2O4 based paint coatings exhibit much higher spectral selectivity (as = 0.88-0.91, e100 =0.27-0.35) which is depending on the coating thicknesses than that of coatings using as-burnt powder as pigment (as = 0.83-0.88, e100 = 0.60-0.66). The CuCr2O4-based paint coatings showed no visible degradation after 600 h of condensation test and the performance criterion value is 0.04, indicating that the coatings have excellent long term stability. |
Keyword | Cucr2o4 Powder Sol-gel Combustion Spectrally Selective Paint Coatings Durability |
Subject Area | 环境材料与生态化学 |
DOI | 10.1007/s10971-011-2625-2 |
Funding Organization | the ‘‘Western Light’’ Talents Training Program of CAS;the Solar Action Plan of CAS (Grant 1731012394) and National Natural Science Foundation of China (Grant 51003111) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 材料与农业工程组;聚合物摩擦学组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/2551 |
Collection | 环境材料与生态化学研究发展中心 固体润滑国家重点实验室(LSL) |
Corresponding Author | Liu G(刘刚) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Res & Dev Ctr Ecomat & Ecochem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Geng QF,Zhao X,Gao XH,et al. Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints[J]. Journal of Sol-Gel Science and Technology,2012,61(1):281-288. |
APA | Geng QF,Zhao X,Gao XH,Yang SR,Liu G,&刘刚.(2012).Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints.Journal of Sol-Gel Science and Technology,61(1),281-288. |
MLA | Geng QF,et al."Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints".Journal of Sol-Gel Science and Technology 61.1(2012):281-288. |
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2012616281288.pdf(629KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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