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Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints
Department环境材料与生态化学研究发展中心
Geng QF(耿庆芬)2,3; Zhao X(赵鑫)1; Gao XH(高祥虎)1; Yang SR(杨生荣)2; Liu G(刘刚)1; Liu G(刘刚)
The second department固体润滑国家重点实验室
2012
Source PublicationJournal of Sol-Gel Science and Technology
ISSN0928-0707
Volume61Issue:1Pages:281-288
AbstractCuCr2O4 spinel powder with high quality black hue, investigated as solar-absorbing pigment for spectrally selective paint, was synthesized by an environmental friendly sol-gel combustion process using citric acid as the fuel and metal nitrates as oxidizers. Single-phase CuCr2O4 spinel crystals were obtained after heat treatment of the as burnt powder at a low temperature (600 C) and the average crystallite size of the CuCr2O4 powders increased with the calcining temperature. Morphological analysis of powders calcined at various temperatures was done by field emission scanning electron microscopy. CuCr2O4 powder calcined at 700 C was chosen as pigment to fabricate thickness sensitive spectrally selective paint coatings by simple spray-coating technique. For the sake of comparison, the as-burnt powder composed of mixed metal oxides (i.e., CuO and Cr2O3) was also used as pigment. The results reveal that the spinel CuCr2O4 based paint coatings exhibit much higher spectral selectivity (as = 0.88-0.91, e100 =0.27-0.35) which is depending on the coating thicknesses than that of coatings using as-burnt powder as pigment (as = 0.83-0.88, e100 = 0.60-0.66). The CuCr2O4-based paint coatings showed no visible degradation after 600 h of condensation test and the performance criterion value is 0.04, indicating that the coatings have excellent long term stability.
KeywordCucr2o4 Powder Sol-gel Combustion Spectrally Selective Paint Coatings Durability
Subject Area环境材料与生态化学
DOI10.1007/s10971-011-2625-2
Funding Organizationthe ‘‘Western Light’’ Talents Training Program of CAS;the Solar Action Plan of CAS (Grant 1731012394) and National Natural Science Foundation of China (Grant 51003111)
Indexed BySCI
Language英语
Funding Project材料与农业工程组;聚合物摩擦学组
compositor第一作者单位
Citation statistics
Cited Times:56[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/2551
Collection环境材料与生态化学研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorLiu G(刘刚)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Res & Dev Ctr Ecomat & Ecochem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Geng QF,Zhao X,Gao XH,et al. Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints[J]. Journal of Sol-Gel Science and Technology,2012,61(1):281-288.
APA Geng QF,Zhao X,Gao XH,Yang SR,Liu G,&刘刚.(2012).Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints.Journal of Sol-Gel Science and Technology,61(1),281-288.
MLA Geng QF,et al."Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints".Journal of Sol-Gel Science and Technology 61.1(2012):281-288.
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