Transition-Metal-Free Reductive Deoxygenative Olefination with CO2

doi:10.1021/acs.orglett.8b01155

LICP OpenIR

	Transition-Metal-Free Reductive Deoxygenative Olefination with CO2
Department	OSSO国家重点实验室
	Zhu Dao-Yong ; Li Wen-Duo ; Yang Ce ; Jie Chen ; Xia Ji-Bao
The second department	夏纪宝人才团队
	2018-05-15
Source Publication	Org. Lett.
Issue	20 Pages:3282−3285
Abstract	A new transition-metal-free reductive deoxygenative olefination of phosphorus ylides with CO2, an abundant and sustainable C1 chemical feedstock, is described. This catalytic CO2 fixation afforded β-unsubstituted acrylates and vinyl ketones in good yields with broad scope and good functional group tolerance under mild reaction conditions. Cost-effective and easily handled polymethylhydrosiloxane was used as a reductant. Bis(silyl)acetal was proved to be the key intermediate in this reductive functionalization of CO2
MOST Discipline Catalogue	理学::化学
DOI	10.1021/acs.orglett.8b01155
URL	查看原文
If	6.492
Language	英语
compositor	第一作者单位
Citation statistics	Cited Times:22[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/24728
Collection	中国科学院兰州化学物理研究所
Corresponding Author	Xia Ji-Bao
Affiliation	1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 4.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 5.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
Recommended Citation GB/T 7714	Zhu Dao-Yong,Li Wen-Duo,Yang Ce,et al. Transition-Metal-Free Reductive Deoxygenative Olefination with CO2[J]. Org. Lett.,2018(20):3282−3285.
APA	Zhu Dao-Yong,Li Wen-Duo,Yang Ce,Jie Chen,&Xia Ji-Bao.(2018).Transition-Metal-Free Reductive Deoxygenative Olefination with CO2.Org. Lett.(20),3282−3285.
MLA	Zhu Dao-Yong,et al."Transition-Metal-Free Reductive Deoxygenative Olefination with CO2".Org. Lett. .20(2018):3282−3285.

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