DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane

doi:10.1002/adsc.201800140

LICP OpenIR

	DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane
Department	羰基合成与选择氧化国家重点实验室（OSSO）
	Li Gang ; Chen Jie ; Zhu Dao-Yong ; Chen Ye ; Xia Ji-Bao
The second department	夏纪宝人才团队
	2018-05-02
Source Publication	Adv. Synth. Catal.
Issue	360 Pages:2364 – 2369
Abstract	We describe herein an efficient organocatalytic system for the selective N-methylation and Nformylation of amines with carbon dioxide (CO2) as a sustainable C1 feedstock and polymethylhydrosiloxane (PMHS) as a cost-effectvie reducing reagent. High-yielding N-methylation products are obtained with low catalyst loading (1%) of DBU. Selective N-formylation of amines is achieved using the same catalytic system at a lower reaction temperature
Keyword	Carbon Dioxide Reduction Methylation Formylation Catalysis
MOST Discipline Catalogue	理学::化学
DOI	10.1002/adsc.201800140
URL	查看原文
Indexed By	SCI
If	5.123
Language	英语
compositor	第一作者单位
Citation statistics	Cited Times:61[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/24725
Collection	中国科学院兰州化学物理研究所
Corresponding Author	Chen Ye; Xia Ji-Bao
Affiliation	1.School Chemistry of Chemical Engineering, Guizhou University 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 4.School Chemistry of Chemical Engineering, Guizhou University 5.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou
Recommended Citation GB/T 7714	Li Gang,Chen Jie,Zhu Dao-Yong,et al. DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane[J]. Adv. Synth. Catal.,2018(360):2364 – 2369.
APA	Li Gang,Chen Jie,Zhu Dao-Yong,Chen Ye,&Xia Ji-Bao.(2018).DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane.Adv. Synth. Catal.(360),2364 – 2369.
MLA	Li Gang,et al."DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane".Adv. Synth. Catal. .360(2018):2364 – 2369.

Files in This Item:
File Name/Size	DocType	Version	Access	License
3 Adv. Synth. Catal.（2490KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	View Application Full Text

File name:	3 Adv. Synth. Catal. 2018, 360, 2364– 2369.pdf
Format:	Adobe PDF

If you have any objections to this item, please fill out the form below and the administrator will contact you as soon as possible.
Content:
Email：	*
Institution:
Verification Code:	Refresh

Any comments and suggestions are welcomed.
Title:	*
Content:
Email：	*
Verification Code:	Refresh

中国科学院兰州化学物理研究所机构知识库