| Alkoxycarbonylation of olefins with carbon dioxide by reusable heterobimetallic ruthenium-cobalt catalytic system | |
| Department | OSSO国家重点实验室 |
Zhang, Xuehua1,3,4; Shen, Chaoren1 ; Tian, Xinxin2; Xia, Chungu1; He, Lin1
| |
| The second department | 苏州研究院 |
| 2018-11 | |
| Source Publication | Green Chemistry
 |
| Volume | 20Issue:24Pages:6231-6238 |
| Abstract | The heterobimetallic ruthenium-cobalt catalytic system exhibited good catalytic performance and reusability in the reductive alkoxycarbonylation of olefins with carbon dioxide. Comparing to the previous system only consisting of ruthenium catalyst, binary catalyst system effectively reduced the usage of noble metal and ionic liquid additive. The respective contribution of ruthenium and cobalt catalysts in this multiple-step catalytic process was investigated by a series of condition-control experiments. The evolution of ruthenium catalyst and the occurrence of alkene hydrogenation during the reaction was explained by theortical calculation. |
| Subject Area | 物理化学与绿色催化 |
| MOST Discipline Catalogue | 理学::化学 |
| DOI | 10.1039/C8GC02289E |
| URL | 查看原文 |
| Indexed By | SCI |
| If | 8.586 |
| Language | 英语 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/24418 |
| Collection | 苏州研究院 中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Tian, Xinxin; Xia, Chungu; He, Lin |
| Affiliation | 1.中国科学院兰州化学物理研究所苏州研究院 2.山西大学 3.中国科学院大学 4.盐城师范学院 |
| Corresponding Author Affilication | Lanzhou Institute of Chemical Physics，Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Zhang, Xuehua,Shen, Chaoren,Tian, Xinxin,et al. Alkoxycarbonylation of olefins with carbon dioxide by reusable heterobimetallic ruthenium-cobalt catalytic system[J]. Green Chemistry,2018,20(24):6231-6238. |
| APA | Zhang, Xuehua,Shen, Chaoren,Tian, Xinxin,Xia, Chungu,&He, Lin.(2018).Alkoxycarbonylation of olefins with carbon dioxide by reusable heterobimetallic ruthenium-cobalt catalytic system.Green Chemistry,20(24),6231-6238. |
| MLA | Zhang, Xuehua,et al."Alkoxycarbonylation of olefins with carbon dioxide by reusable heterobimetallic ruthenium-cobalt catalytic system".Green Chemistry 20.24(2018):6231-6238. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c8gc02289e.pdf（576KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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