| Palladium-Catalyzed Hydroaminocarbonylation of Alkynes with Tertiary Amines via C-N Bond Cleavage | |
| Department | OSSO国家重点实验室 |
Gao B(高宝)1; Huang HM(黄汉民)1,2,3 ; Huang HM(黄汉民)
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| 2017 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 19Issue:22Pages:6260-6263 |
| Abstract | An efficient strategy for the cleavage of the C–N bond of tertiary amines was developed with DTBP as an oxidant, in which the cleaved H atom and amine moiety were successfully transferred to the desired products. This strategy has enabled an efficient palladium-catalyzed hydroaminocarbonylation of alkynes with tertiary amines. Notably, the catalyst loading could be lowered from 5 to 0.1 mol %, which represents the lowest catalyst loading among the reported work on carbonylation via C–N bond activation. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acs.orglett.7b03331 |
| Funding Organization | the CAS Interdisciplinary Innovation Team, the National Natural Science Foundation of China (21672199;21702197);the Fundamental Research Funds for the Central Universities and the Anhui Provincial Natural Science Foundation (1708085MB28) |
| Indexed By | SCI |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/23806 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | 1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Gao B,Huang HM,Huang HM. Palladium-Catalyzed Hydroaminocarbonylation of Alkynes with Tertiary Amines via C-N Bond Cleavage[J]. Organic Letters,2017,19(22):6260-6263. |
| APA | Gao B,Huang HM,&黄汉民.(2017).Palladium-Catalyzed Hydroaminocarbonylation of Alkynes with Tertiary Amines via C-N Bond Cleavage.Organic Letters,19(22),6260-6263. |
| MLA | Gao B,et al."Palladium-Catalyzed Hydroaminocarbonylation of Alkynes with Tertiary Amines via C-N Bond Cleavage".Organic Letters 19.22(2017):6260-6263. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.orglett.7b03331.（713KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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