| Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes | |
| Department | 苏州研究院 |
| Lv, Ji-Yuan1; Xu, Zheng1; Zheng ZJ(郑战江)1; Li, Li1; Cui, Yu-Ming1; Cao, Jian1; Yang KF(杨科芳)1; Xu LW(徐利文)1,2; Xu LW(徐利文) | |
| The second department | osso国家重点实验室 |
| 2017 | |
| Source Publication | RSC Advances
 |
| ISSN | 2046-2069 |
| Volume | 7Issue:87Pages:54934-54938 |
| Abstract | The catalytic asymmetric copper-catalyzed conjugate addition of diethylzinc to α,β-unsaturated acylsilanes was found to proceed smoothly in moderate to good yields and promising enantioselectivities (up to 85% ee) in the presence of the multifunctional HZNU-Phos with both a phosphine center and BINOL-based diol moiety that played a crucial role in the achievement of the best enantioselectivity for this reaction. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c7ra11919d |
| Funding Organization | the National Natural Science Foundation of China (No. 21472031;21703051;21773051);Zhejiang Provincial Natural Science Foundation of China (LZ18B020001;LY16E030009;LY17B030005;LY17E030003);Science and Technology Department of Zhejiang Province (2015C31138) |
| Indexed By | SCI |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/23789 |
| Collection | 苏州研究院 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li, Li; Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, 1378 Wenyi West Rd,Sci Pk HZNU, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Suzhou Res Insititue, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Lv, Ji-Yuan,Xu, Zheng,Zheng ZJ,et al. Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes[J]. RSC Advances,2017,7(87):54934-54938. |
| APA | Lv, Ji-Yuan.,Xu, Zheng.,Zheng ZJ.,Li, Li.,Cui, Yu-Ming.,...&徐利文.(2017).Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes.RSC Advances,7(87),54934-54938. |
| MLA | Lv, Ji-Yuan,et al."Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes".RSC Advances 7.87(2017):54934-54938. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c7ra11919d.pdf（577KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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