| Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes | |
| Department | OSSO国家重点实验室 |
Qin GP(秦贵平)1,3; Wang Y(王永)1; Huang HM(黄汉民)1,2 ; Huang HM(黄汉民)
| |
| 2017 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 19Issue:23Pages:6352-6355 |
| Abstract | Higher π-extended naphthalene, contained in methylnaphthalenes, which could capture alkyl radicals via SOMO–LUMO interactions, enabled the development of Cu-catalyzed formal [4 + 2] and [3 + 2] cycloadditions between methylnaphthalenes and electron-deficient alkenes. Under copper catalysis, a series of electron-deficient alkenes and methylnaphthalenes with different substituents were successfully incorporated with di-tert-butyl peroxide (TBP) as an oxidant and radical initiator, providing a wide range of cycloadducts. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1021/acs.orglett.7b03194 |
| Funding Organization | the CAS Interdisciplinary Innovation Team ; the National Natural Science Foundation of China (21672199) |
| Indexed By | SCI |
| If | 6.492 |
| Language | 英语 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/23782 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Qin GP,Wang Y,Huang HM,et al. Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes[J]. Organic Letters,2017,19(23):6352-6355. |
| APA | Qin GP,Wang Y,Huang HM,&Huang HM.(2017).Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes.Organic Letters,19(23),6352-6355. |
| MLA | Qin GP,et al."Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes".Organic Letters 19.23(2017):6352-6355. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 20176352-6355.pdf（1050KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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