Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction | |
Department | OSSO国家重点实验室 |
Wang, Pengxin1; Wang, Jie1; Wang, Linqing1; Li, Dan1; Wang, Kezhou1; Liu, Yuyang1; Zhu, Haiyong1; Liu, Xihong1; Yang, Dongxu1; Wang R(王锐)1,2; Wang R(王锐) | |
2018 | |
Source Publication | Advanced Synthesis and Catalysis |
ISSN | 1615-4150 |
Volume | 360Issue:3Pages:401-405 |
Abstract | Axial naphthols are applied in asymmetric halogenative dearomatization reactions under simple and mild conditions in the work presented herein. The axial‐to‐central chirality conversion is efficiently accomplished, and the desired halogenated dearomatization products are obtained in high yields and enantioselectivities. By using commercially available halogenation reagents, the asymmetric fluorinative, chlorinative and brominative dearomatization reactions of axial naphthols derived from BINOLs are achieved. (BINOL=1,1′‐Bi‐2‐naphthol) |
Keyword | Naphthols Dearomatization Halogenated Asymmetric Synthesis |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/adsc.201700745 |
Funding Organization | the NSFC (21432003;81473095;21602091);the Program for Chang-jiang Scholars and Innovative Research Team in University (PCSIRT: No. IRT_15R27);Special Research Found for the Doctoral Program of Higher Education (20130211130005);the Fundamental Research Funds for the Central Universities (lzujbky-2015-282;lzujbky-2016-ct01) |
Indexed By | SCI |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23756 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Yang, Dongxu; Wang R(王锐) |
Affiliation | 1.Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Pengxin,Wang, Jie,Wang, Linqing,et al. Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction[J]. Advanced Synthesis and Catalysis,2018,360(3):401-405. |
APA | Wang, Pengxin.,Wang, Jie.,Wang, Linqing.,Li, Dan.,Wang, Kezhou.,...&王锐.(2018).Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction.Advanced Synthesis and Catalysis,360(3),401-405. |
MLA | Wang, Pengxin,et al."Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction".Advanced Synthesis and Catalysis 360.3(2018):401-405. |
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Wang_et_al-2018-Adva(1207KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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