LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction
DepartmentOSSO国家重点实验室
Wang, Pengxin1; Wang, Jie1; Wang, Linqing1; Li, Dan1; Wang, Kezhou1; Liu, Yuyang1; Zhu, Haiyong1; Liu, Xihong1; Yang, Dongxu1; Wang R(王锐)1,2; Wang R(王锐)
2018
Source PublicationAdvanced Synthesis and Catalysis
ISSN1615-4150
Volume360Issue:3Pages:401-405
Abstract

Axial naphthols are applied in asymmetric halogenative dearomatization reactions under simple and mild conditions in the work presented herein. The axial‐to‐central chirality conversion is efficiently accomplished, and the desired halogenated dearomatization products are obtained in high yields and enantioselectivities. By using commercially available halogenation reagents, the asymmetric fluorinative, chlorinative and brominative dearomatization reactions of axial naphthols derived from BINOLs are achieved. (BINOL=1,1′‐Bi‐2‐naphthol)

KeywordNaphthols Dearomatization Halogenated Asymmetric Synthesis
Subject Area物理化学与绿色催化
DOI10.1002/adsc.201700745
Funding Organizationthe NSFC (21432003;81473095;21602091);the Program for Chang-jiang Scholars and Innovative Research Team in University (PCSIRT: No. IRT_15R27);Special Research Found for the Doctoral Program of Higher Education (20130211130005);the Fundamental Research Funds for the Central Universities (lzujbky-2015-282;lzujbky-2016-ct01)
Indexed BySCI
Language英语
compositor第二作者单位
Citation statistics
Cited Times:33[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/23756
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorYang, Dongxu; Wang R(王锐)
Affiliation1.Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Gansu, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China
Recommended Citation
GB/T 7714
Wang, Pengxin,Wang, Jie,Wang, Linqing,et al. Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction[J]. Advanced Synthesis and Catalysis,2018,360(3):401-405.
APA Wang, Pengxin.,Wang, Jie.,Wang, Linqing.,Li, Dan.,Wang, Kezhou.,...&王锐.(2018).Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction.Advanced Synthesis and Catalysis,360(3),401-405.
MLA Wang, Pengxin,et al."Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction".Advanced Synthesis and Catalysis 360.3(2018):401-405.
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