Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids | |
Department | 固体润滑国家重点实验室 |
Yao, Meihuan1,2; Li, Qing1; Xia YQ(夏延秋)3; Liang YM(梁永民)2 | |
2018 | |
Source Publication | Russian Journal of Physical Chemistry A |
ISSN | 0036-0244 |
Volume | 92Issue:3Pages:502-507 |
Abstract | A series of novel ionic liquids based on naphthyl-functionalized imidazolium cation have been prepared. Their structure was characterized by NMR. The thermal stabilities of the prepared liquids were studied by thermal gravimetric analysis. The new ionic liquids containing NTf-2 anion display significantly higher thermal stabilities (>400°C). Anion exchange to PF-6, BF-4, and Br– decreases the thermal stabilities of such ionic liquids. Fluorescence and UV–Vis absorption spectroscopy were used to study the spectroscopic properties of the ionic liquids. Compared with common ionic liquids, the described ionic liquids provide robust fluorescence properties and remarkably increased UV–Vis absorption. This research may enrich the field of functionalized ionic liquids and provide a platform for extension of ionic liquid applications. |
Keyword | Ionic Liquids Spectroscopy Naphtyl-functionalized Thermal Analyses Fluorescence Uv-vis Absorption |
Subject Area | 材料科学与物理化学 |
DOI | 10.1134/S0036024418030196 |
Funding Organization | Key Scientific Research Project of Higher Education of Henan Province (no. 17A150032);an open fund of the State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, China (grant no. LSL-1507) |
Indexed By | SCI |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23694 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Yao, Meihuan |
Affiliation | 1.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China 3.North China Elect Power Univ, Sch Energy & Mech Engn, Beijing 102206, Peoples R China |
Recommended Citation GB/T 7714 | Yao, Meihuan,Li, Qing,Xia YQ,et al. Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids[J]. Russian Journal of Physical Chemistry A,2018,92(3):502-507. |
APA | Yao, Meihuan,Li, Qing,Xia YQ,&Liang YM.(2018).Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids.Russian Journal of Physical Chemistry A,92(3),502-507. |
MLA | Yao, Meihuan,et al."Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids".Russian Journal of Physical Chemistry A 92.3(2018):502-507. |
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S0036024418030196.pd(434KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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