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Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids
Department固体润滑国家重点实验室
Yao, Meihuan1,2; Li, Qing1; Xia YQ(夏延秋)3; Liang YM(梁永民)2
2018
Source PublicationRussian Journal of Physical Chemistry A
ISSN0036-0244
Volume92Issue:3Pages:502-507
Abstract

A series of novel ionic liquids based on naphthyl-functionalized imidazolium cation have been prepared. Their structure was characterized by NMR. The thermal stabilities of the prepared liquids were studied by thermal gravimetric analysis. The new ionic liquids containing NTf-2 anion display significantly higher thermal stabilities (>400°C). Anion exchange to PF-6, BF-4, and Br decreases the thermal stabilities of such ionic liquids. Fluorescence and UV–Vis absorption spectroscopy were used to study the spectroscopic properties of the ionic liquids. Compared with common ionic liquids, the described ionic liquids provide robust fluorescence properties and remarkably increased UV–Vis absorption. This research may enrich the field of functionalized ionic liquids and provide a platform for extension of ionic liquid applications.

KeywordIonic Liquids Spectroscopy Naphtyl-functionalized Thermal Analyses Fluorescence Uv-vis Absorption
Subject Area材料科学与物理化学
DOI10.1134/S0036024418030196
Funding OrganizationKey Scientific Research Project of Higher Education of Henan Province (no. 17A150032);an open fund of the State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, China (grant no. LSL-1507)
Indexed BySCI
Language英语
compositor第二作者单位
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/23694
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorYao, Meihuan
Affiliation1.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China
3.North China Elect Power Univ, Sch Energy & Mech Engn, Beijing 102206, Peoples R China
Recommended Citation
GB/T 7714
Yao, Meihuan,Li, Qing,Xia YQ,et al. Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids[J]. Russian Journal of Physical Chemistry A,2018,92(3):502-507.
APA Yao, Meihuan,Li, Qing,Xia YQ,&Liang YM.(2018).Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids.Russian Journal of Physical Chemistry A,92(3),502-507.
MLA Yao, Meihuan,et al."Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids".Russian Journal of Physical Chemistry A 92.3(2018):502-507.
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