| Surface Modification of Attapulgite Nanorods with Nitrile Butadiene Rubber via Thiol-Ene Interfacial Click Reaction: Grafting or Crosslinking | |
| Department | 甘肃省黏土矿物应用重点实验室 |
| Pan, Changou1; Liu, Peng1,2 | |
| 2018 | |
| Source Publication | Industrial && Engineering Chemistry Research
 |
| ISSN | 0888-5885 |
| Volume | 57Issue:14Pages:4949-4954 |
| Abstract | A versatile approach was developed for the preparation of cross-linked attapulgite (ATP)-nitrile butadiene rubber (NBR) nanocomposites or NBR grafted ATP nanorods, by facilely adjusting the feeding ratio between the butadiene-based rubbers and the thiol-modified attapulgite (ATP-SH) nanorods in a facile thermal-triggered thiol–ene interfacial click reaction. The modified products with different feeding ratios between the ATP-SH and NBR were characterized with FT-IR, TGA, and TEM techniques. The results indicated that the cross-linked ATP-NBR nanocomposites could be produced via the thiol–ene interfacial click reaction with excess NBR, while the NBR grafted ATP nanorods could be synthesized via the reaction with excess ATP-SH nanorods. Based on the results, a possible mechanism and potential applications were proposed. |
| Subject Area | 环境材料与生态化学 |
| DOI | 10.1021/acs.iecr.8b00094 |
| Funding Organization | the Foundation of Key Laboratory of Clay Mineral Applied Research of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences (CMAR-03) |
| Indexed By | SCI |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/23672 |
| Collection | 甘肃省黏土矿物应用研究重点实验室 |
| Corresponding Author | Liu, Peng |
| Affiliation | 1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Clay Mineral Appl Res Gansu Prov, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Pan, Changou,Liu, Peng. Surface Modification of Attapulgite Nanorods with Nitrile Butadiene Rubber via Thiol-Ene Interfacial Click Reaction: Grafting or Crosslinking[J]. Industrial && Engineering Chemistry Research,2018,57(14):4949-4954. |
| APA | Pan, Changou,&Liu, Peng.(2018).Surface Modification of Attapulgite Nanorods with Nitrile Butadiene Rubber via Thiol-Ene Interfacial Click Reaction: Grafting or Crosslinking.Industrial && Engineering Chemistry Research,57(14),4949-4954. |
| MLA | Pan, Changou,et al."Surface Modification of Attapulgite Nanorods with Nitrile Butadiene Rubber via Thiol-Ene Interfacial Click Reaction: Grafting or Crosslinking".Industrial && Engineering Chemistry Research 57.14(2018):4949-4954. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| acs.iecr.8b00094.pdf（5054KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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