Morphology-Controlled Synthesis of Molybdenum Disulfide Wrapped Single-Walled Carbon Nanotubes for the Hydrogen Evolution Reaction | |
Department | 苏州研究院 |
Chen, Lin1; Ceng M(曾敏)2; Zhang, Wenqing1; He L(何林)2; He, Wenya1; Yang, Fengchun1; Zhang, Xin1 | |
The second department | osso国家重点实验室 |
2018 | |
Source Publication | ChemCatChem |
ISSN | 1867-3880 |
Volume | 10Issue:5Pages:1128-1133 |
Abstract | The synthesis of new nanohybrid catalysts with a tunable structure and the exploration of their synergistic behaviors have captured substantial attention. In this work, amorphous molybdenum disulfide/single‐walled carbon nanotubes (MoS2/SWNTs) composites are synthesized by a facile hydrothermal process with the assistance of l‐cysteine. We varied the mass ratio of sodium molybdate (the in situ Mo source) to SWNTs, this method provides a well‐defined pathway to enable the morphological control over the evolution of MoS2 from nanospheres to nanofilaments, nanorods, and nanosheets. Among the as‐obtained samples, the MoS2/SWNTs (1:1) hybrids, which displayed a 3 D architecture that consisted of nanorods, exhibited the highest activity in the hydrogen evolution reaction (HER). Compared with pure MoS2, the MoS2 nanosheets that decorate the SWNTs have more highly exposed active edges, and the SWNTs in the center of the MoS2/SWNTs nanorods can enhance the conductivity. We regulated the ratio between MoS2 and SWNTs to obtain a balance between the number of active sites and the conductivity of MoS2/SWNTs. Here, MoS2/SWNTs nanorods exhibited a low overpotential of 195 mV at 20 mA cm−2 and a low Tafel slope of 41 mV dec−1 for MoS2‐based HER catalysts. |
Keyword | Electrochemistry Hydrogen Molybdenum Nanostructures Structure-property Relationships |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/cctc.201701403 |
Funding Organization | the National Natural Scientific Foundation of China (No. 21405120);the Shaanxi Provincial Science and Technology Development Funds (No. 2016KW-061);Graduate Student Independent Innovation Project Foundation of Northwest University (No. YZZ15043);the “Top-rated Discipline” construction Scheme of Shaanxi higher education |
Indexed By | SCI |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/23669 |
Collection | 苏州研究院 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Yang, Fengchun; Zhang, Xin |
Affiliation | 1.Northwest Univ Xian, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710127, Shaanxi, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Chen, Lin,Ceng M,Zhang, Wenqing,et al. Morphology-Controlled Synthesis of Molybdenum Disulfide Wrapped Single-Walled Carbon Nanotubes for the Hydrogen Evolution Reaction[J]. ChemCatChem,2018,10(5):1128-1133. |
APA | Chen, Lin.,Ceng M.,Zhang, Wenqing.,He L.,He, Wenya.,...&Zhang, Xin.(2018).Morphology-Controlled Synthesis of Molybdenum Disulfide Wrapped Single-Walled Carbon Nanotubes for the Hydrogen Evolution Reaction.ChemCatChem,10(5),1128-1133. |
MLA | Chen, Lin,et al."Morphology-Controlled Synthesis of Molybdenum Disulfide Wrapped Single-Walled Carbon Nanotubes for the Hydrogen Evolution Reaction".ChemCatChem 10.5(2018):1128-1133. |
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