| Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors | |
| Department | OSSO国家重点实验室 |
| Li, Tian-Ren1; Wang, Ya-Ni1; Xiao, Wen-Jing1,2; Lu, Liang-Qiu1,3 | |
| 2018 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 0040-4039 |
| Volume | 59Issue:16Pages:1521-1530 |
| Abstract | Vinyl and ethynyl benzoxazinones have recently received increasing attention from organic chemists because they are powerful tools for the construction of structurally diverse aza-heterocycles. A number of catalytic cyclization reactions have been developed that used these two reagents and required the presence of a transition-metal catalyst (i.e., palladium, iron, and copper). This review highlights the design and synthesis of these versatile reagents, and their applications as precursors for transition-metal-containing 1,4-dipoles in dipolar cyclizations and related cascade reactions. The general mechanisms and asymmetric inductions are briefly discussed as well. |
| Keyword | Benzoxazinone Heterocycle Synthesis Dipolar Cyclization Transition Metal Catalysis |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.tetlet.2018.02.081 |
| Funding Organization | the National Natural Science Foundation of China (NO. 21572074;21772052;21772053);the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019);the Foundation for the Author of National Excellent Doctoral Dissertation of PR China (NO. 201422);the Natural Science Foundation of Hubei Province (2015CFA033;2017AH047) |
| Indexed By | SCI |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/23632 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Lu, Liang-Qiu |
| Affiliation | 1.CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China 2.State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China 3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China |
| Recommended Citation GB/T 7714 | Li, Tian-Ren,Wang, Ya-Ni,Xiao, Wen-Jing,et al. Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors[J]. Tetrahedron Letters,2018,59(16):1521-1530. |
| APA | Li, Tian-Ren,Wang, Ya-Ni,Xiao, Wen-Jing,&Lu, Liang-Qiu.(2018).Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors.Tetrahedron Letters,59(16),1521-1530. |
| MLA | Li, Tian-Ren,et al."Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors".Tetrahedron Letters 59.16(2018):1521-1530. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S004040391830（1819KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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