A Regioselective Synthesis of 2,5-Diaryl Oxazoles via TsOH/I2-Mediated Cascade Cyclization | |
Department | ERC国家工程研究中心 |
Zhang FD(张芳东)1; Wang J(王静)1; Zhang XG(张学国)1; Meng X(孟旭)2; Chen BH(陈保华)1; Chen BH(陈保华) | |
The second department | 苏州研究院;osso国家重点实验室 |
2017 | |
Source Publication | ChemistrySelect |
ISSN | 2365-6549 |
Volume | 2Issue:28Pages:8717-8720 |
Abstract | A concise and practical approach for synthesis of 2,5-disubstituted oxazole has been developed via a TsOH(p-Methylbenzene sulfonic acid)/I2-mediated tandem dehydrogenation oxidative cyclization of phenylacetylene and benzylamine. Desired products in high yields have been obtained. |
Keyword | Dehydrogenation Oxidative Cyclization Metal-freecatalyzed Nitrogen Heterocycles Special Decarboxylation |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/slct.201701390 |
Funding Organization | the National Natural Science Foundation of China (Nos. 21372102;21403256) |
Language | 英语 |
Funding Project | 催化新工艺研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22816 |
Collection | 精细石油化工中间体国家工程研究中心(ERC) 羰基合成与选择氧化国家重点实验室(OSSO) 苏州研究院 |
Corresponding Author | Chen BH(陈保华) |
Affiliation | 1.State Key Laboratory of Applied Organic Chemistry Lanzhou University, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province Lanzhou 730000, P. R. of China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences Lanzhou 730000, P. R. of China |
Recommended Citation GB/T 7714 | Zhang FD,Wang J,Zhang XG,et al. A Regioselective Synthesis of 2,5-Diaryl Oxazoles via TsOH/I2-Mediated Cascade Cyclization[J]. ChemistrySelect,2017,2(28):8717-8720. |
APA | Zhang FD,Wang J,Zhang XG,Meng X,Chen BH,&陈保华.(2017).A Regioselective Synthesis of 2,5-Diaryl Oxazoles via TsOH/I2-Mediated Cascade Cyclization.ChemistrySelect,2(28),8717-8720. |
MLA | Zhang FD,et al."A Regioselective Synthesis of 2,5-Diaryl Oxazoles via TsOH/I2-Mediated Cascade Cyclization".ChemistrySelect 2.28(2017):8717-8720. |
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2017-Chem. Select.pd(1205KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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