Direct Allylic C-H Bond Activation To Synthesize [Pd(eta(3)-cin)(IPr)CI] Complex: Application in the Allylation of Oxindoles | |
Department | OSSO国家重点实验室 |
Hu RB(胡荣斌)1,2; Wang, Chun-Hai1; Ren, Wei1; Liu, Zhong1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
2017 | |
Source Publication | ACS Catalysis |
ISSN | 2155-5435 |
Volume | 7Issue:11Pages:7400-7404 |
Abstract | N-heterocyclic carbenes (NHCs) was uncovered as an efficient ligand in promoting allylic C–H bond functionlizations. Notably, the catalytic [Pd(η3-cin)(IPr)Cl] complex (where cin = cinnamyl) was formed in situ from direct C–H activation of allylic precursors, and was obtained by way of one-pot strategy with available IPr·HCl and allylbenzene. The catalyst exhibits high regioselectivity and stereoselectivity of the allylic C–H alkylation with oxindoles with a broad scope. |
Keyword | [Pd(Η3-cin)(Ipr)Cl] Allylic C-h Activation Alkylation Oxindoles Selectivity-control |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/acscatal.7b02965 |
Funding Organization | the NSFC (Nos. 21472076;21532001);Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_15R28) |
Indexed By | SCI |
If | 10.614 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22755 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Yang SD(杨尚东) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Hu RB,Wang, Chun-Hai,Ren, Wei,et al. Direct Allylic C-H Bond Activation To Synthesize [Pd(eta(3)-cin)(IPr)CI] Complex: Application in the Allylation of Oxindoles[J]. ACS Catalysis,2017,7(11):7400-7404. |
APA | Hu RB,Wang, Chun-Hai,Ren, Wei,Liu, Zhong,Yang SD,&杨尚东.(2017).Direct Allylic C-H Bond Activation To Synthesize [Pd(eta(3)-cin)(IPr)CI] Complex: Application in the Allylation of Oxindoles.ACS Catalysis,7(11),7400-7404. |
MLA | Hu RB,et al."Direct Allylic C-H Bond Activation To Synthesize [Pd(eta(3)-cin)(IPr)CI] Complex: Application in the Allylation of Oxindoles".ACS Catalysis 7.11(2017):7400-7404. |
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acscatal.7b02965.pdf(1726KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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