Ir(III)-Catalyzed Direct C-H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis | |
Department | OSSO国家重点实验室 |
Liu, Zhong1; Wu, Ji-Qiang1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
2017 | |
Source Publication | Organic Letters |
ISSN | 1523-7060 |
Volume | 19Issue:19Pages:5434-5437 |
Abstract | Diazo compounds as coupling partners are efficiently applied to Ir(III)-catalyzed direct C–H functionalization of arylphosphine oxides. Involving C–H activation, carbene insertion, and tautomerism, this reaction proceeds under mild conditions, thus proving an approach to the synthesis of MOP-type ligand precursor in a single step. The utility of this transformation has been further demonstrated in ligand synthesis as well as in the construction of phosphole framework. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/acs.orglett.7b02710 |
Funding Organization | the NSFC (Nos. 21472076;21532001);PCSIRT (IRT_15R28;lzujbky-2016-ct02) |
Indexed By | SCI |
If | 6.579 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22533 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Yang SD(杨尚东) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Liu, Zhong,Wu, Ji-Qiang,Yang SD,et al. Ir(III)-Catalyzed Direct C-H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis[J]. Organic Letters,2017,19(19):5434-5437. |
APA | Liu, Zhong,Wu, Ji-Qiang,Yang SD,&杨尚东.(2017).Ir(III)-Catalyzed Direct C-H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis.Organic Letters,19(19),5434-5437. |
MLA | Liu, Zhong,et al."Ir(III)-Catalyzed Direct C-H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis".Organic Letters 19.19(2017):5434-5437. |
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