| Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines | |
| Department | 苏州研究院 |
Kuan, Suzie Hui Chin1,2; Sun, Wei1; Wang L(王露)1; Xia CG(夏春谷)1 ; Tay, Meng Guan2; Liu C(刘超)1; Liu C(刘超)
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| The second department | osso国家重点实验室 |
| 2017 | |
| Source Publication | Advanced Synthesis & Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 359Issue:20Pages:3484-3489 |
| Abstract | A novel double carbonylation process has been demonstrated with easily available HCOCOH (glyoxal) as the double carbonylation reagent. Simple CuCl2·2H2O (copper(II) chloride dihydrate) was used as the oxidant for this transformation. Under optimized reaction conditions, various primary and secondary anilines were double- carbonylated to afford their corresponding isatins (26 examples, up to 80% yields). |
| Keyword | Double Carbonylation Glyoxal Isatin Synthesis Anilines |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201700583 |
| Funding Organization | the National Natural Science Foundation of China (21673261;21603245;21633013);the State Key Laboratory for Oxo Synthesis and Selective Oxidation (OSSO), Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences;CAS Interdisciplinary Innovation Team;Young Elite Scientist Sponsorship Program by CAST;MGT and SHCK thank to Malaysian Toray Science Foundation (MTSF) for research financial support under grant number of GL(F07)/MTSF/2014(14) |
| Indexed By | SCI |
| If | 5.646 |
| Language | 英语 |
| Funding Project | 均相催化研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22529 |
| Collection | 苏州研究院 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Liu C(刘超) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Malaysia Sarawak, Fac Resource Sci & Technol, Dept Chem, Kota Samarahan 94300, Sarawak, Malaysia |
| Recommended Citation GB/T 7714 | Kuan, Suzie Hui Chin,Sun, Wei,Wang L,et al. Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines[J]. Advanced Synthesis & Catalysis,2017,359(20):3484-3489. |
| APA | Kuan, Suzie Hui Chin.,Sun, Wei.,Wang L.,Xia CG.,Tay, Meng Guan.,...&刘超.(2017).Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines.Advanced Synthesis & Catalysis,359(20),3484-3489. |
| MLA | Kuan, Suzie Hui Chin,et al."Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines".Advanced Synthesis & Catalysis 359.20(2017):3484-3489. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Z01030730.pdf（2287KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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