In-situ growth of Co3O4 nanoparticles on mesoporous carbon nanofibers: a new nanocomposite for nonenzymatic amperometric sensing of H2O2 | |
Department | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Ni Y(倪月)1,2; Liao Y(廖原)1,2; Zheng, Mingbo3; Shao SJ(邵士俊)1; Shao SJ(邵士俊) | |
2017 | |
Source Publication | Microchimica Acta |
ISSN | 0026-3672 |
Volume | 184Issue:10Pages:3689-3695 |
Abstract | The paper describes a nonenzymatic amperometric H2O2 sensor that uses a nanocomposite consisting of Co3O4 nanoparticles (NPs) and mesoporous carbon nanofibers (Co3O4-MCNFs). The Co3O4 NPs were grown in situ on the MCNFs by a solvothermal procedure. The synergetic combination of the electrocatalytic activity of the Co3O4 NPs and the electrical conductivity of MCNFs as an immobilization matrix enhance the sensing ability of the hybrid nanostructure. The oxidation current, best measured at 0.2 V (vs. SCE) is linear in the 1 to 2580 μM H2O2 concentration range, with a 0.5 μM lower detection limit (at an S/N ratio of 3). The sensor is highly selective even in the presence of common electroactive interferents. It was applied to the determination of H2O2 in spiked milk samples. |
Keyword | Solvothermal Treatment Hybrid Nanostructures Synergistic Effect Electrochemical Detection Alkaline Electrolyte Cyclic Voltammetry H2o2 Oxidation Amperometry |
Subject Area | 分析化学与药物化学 |
DOI | 10.1007/s00604-017-2395-9 |
Funding Organization | the National Natural Science Foundation of China (21275150;51202106);the Funds for Distinguished Young Scientists of Gansu (1210RJDA013) |
Indexed By | SCI |
If | 4.580 |
Language | 英语 |
Funding Project | 药物分子识别研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22483 |
Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
Corresponding Author | Zheng, Mingbo; Shao SJ(邵士俊) |
Affiliation | 1.CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, People’s Republic of China 2.University of Chinese Academy of Sciences, Beijing, People’s Republic of China 3.School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, People’s Republic of China |
Recommended Citation GB/T 7714 | Ni Y,Liao Y,Zheng, Mingbo,et al. In-situ growth of Co3O4 nanoparticles on mesoporous carbon nanofibers: a new nanocomposite for nonenzymatic amperometric sensing of H2O2[J]. Microchimica Acta,2017,184(10):3689-3695. |
APA | Ni Y,Liao Y,Zheng, Mingbo,Shao SJ,&邵士俊.(2017).In-situ growth of Co3O4 nanoparticles on mesoporous carbon nanofibers: a new nanocomposite for nonenzymatic amperometric sensing of H2O2.Microchimica Acta,184(10),3689-3695. |
MLA | Ni Y,et al."In-situ growth of Co3O4 nanoparticles on mesoporous carbon nanofibers: a new nanocomposite for nonenzymatic amperometric sensing of H2O2".Microchimica Acta 184.10(2017):3689-3695. |
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