Formation of organogels with aggregation-induced emission characteristics triggered by thermal and ultrasound | |
Department | 固体润滑国家重点实验室 |
Shen, Jinglin1; Ding, Peng1; Gao, Lei1; Gao, Yuanyuan1; Zhang, Qingyu1; Yuan, Shiling1; Xin, Xia1,2,3 | |
2017 | |
Source Publication | Colloid and Polymer Science |
ISSN | 0303-402X |
Volume | 295Issue:10Pages:1765-1772 |
Abstract | Thermal- and ultrasound-triggered organogels formed by an imidazolium-based salt-free catanionic surfactant 1-tetradecyl-3-methylimidazolium methyl orange [C14mim][MO] in dimethyl formamide (DMF) were investigated. The [C14mim][MO] organogels exhibited luminescent property owing to the aggregation-induced emission (AIE) by noncovalent interaction and displayed excellent mechanical strength and reversible sol–gel transition. Furthermore, the self-assembly behavior of [C14mim][MO] in mixed solvents was also investigated. It can be observed that the addition of poor solvents (toluene, H2O) in DMF weakened the mechanical strength of the gels. Besides, the fluorescence of gel performs opposite changes towards different kinds of solvent that the addition of solvents without benzene ring structure (ethanol and dichloromethane) reduced the fluorescence while the addition of solvents containing benzene ring structure (xylene, aniline) enhanced the fluorescence greatly owing to the π–π stacking of solvent and MO. These results reveal the important role of heat, ultrasound, and solvents in the formation of the supramolecular organogels and may help us to design new soft materials. |
Keyword | Organogel Ultrasound Aggregation-induced Emission Surfactant Dye |
Subject Area | 材料科学与物理化学 |
DOI | 10.1007/s00396-017-4150-5 |
Funding Organization | the National Natural Science Foundation of China (21573130;21173128);Young Scholars Program of Shandong University (2016WLJH20) |
Indexed By | SCI |
If | 1.723 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22478 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Yuan, Shiling; Xin, Xia |
Affiliation | 1.Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Shanda Nanlu 27, Jinan 250100, Shandong, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China 3.Shandong Univ, Natl Engn Technol Res Ctr Colloidal Mat, Shanda Nanlu 27, Jinan 250100, Shandong, Peoples R China |
Recommended Citation GB/T 7714 | Shen, Jinglin,Ding, Peng,Gao, Lei,et al. Formation of organogels with aggregation-induced emission characteristics triggered by thermal and ultrasound[J]. Colloid and Polymer Science,2017,295(10):1765-1772. |
APA | Shen, Jinglin.,Ding, Peng.,Gao, Lei.,Gao, Yuanyuan.,Zhang, Qingyu.,...&Xin, Xia.(2017).Formation of organogels with aggregation-induced emission characteristics triggered by thermal and ultrasound.Colloid and Polymer Science,295(10),1765-1772. |
MLA | Shen, Jinglin,et al."Formation of organogels with aggregation-induced emission characteristics triggered by thermal and ultrasound".Colloid and Polymer Science 295.10(2017):1765-1772. |
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