Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes | |
Department | 苏州研究院 |
Chen, Feng1; Basudev Sahoo1; Carsten Kreyenschulte1; Henrik Lund1; Ceng M(曾敏)2; He L(何林)2; Kathrin Junge1; Matthias Beller1 | |
The second department | osso国家重点实验室 |
2017 | |
Source Publication | Chemical Science |
ISSN | 2041-6520 |
Volume | 8Issue:9Pages:6239-6246 |
Abstract | Nitrogen modified cobalt catalysts supported on carbon were prepared by pyrolysis of the mixture generated from cobalt(II) acetate in aqueous solution of melamine or waste melamine resins, which are widely used as industrial polymers. The obtained nanostructured materials catalyze the transfer hydrogenation of N-heteroarenes with formic acid in the absence of base. The optimal Co/Melamine-2@C-700 catalyst exhibits high activity and selectivity for the dehydrogenation of formic acid into molecular hydrogen and carbon dioxide and allows for the reduction of diverse N-heteroarenes including substrates featuring sensitive functional groups. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c7sc02062g |
Funding Organization | The Federal Ministry of Education and Research (BMBF);the State of Mecklenburg-Vorpommern |
Indexed By | SCI |
If | 8.668 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22471 |
Collection | 苏州研究院 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Matthias Beller |
Affiliation | 1.Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany 2.Chinese Acad Sci, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Chen, Feng,Basudev Sahoo,Carsten Kreyenschulte,et al. Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes[J]. Chemical Science,2017,8(9):6239-6246. |
APA | Chen, Feng.,Basudev Sahoo.,Carsten Kreyenschulte.,Henrik Lund.,Ceng M.,...&Matthias Beller.(2017).Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes.Chemical Science,8(9),6239-6246. |
MLA | Chen, Feng,et al."Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes".Chemical Science 8.9(2017):6239-6246. |
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c7sc02062g.pdf(1507KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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