| The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction | |
| Department | OSSO国家重点实验室 |
Xu DQ(徐大乾)1,2; Sun QS(孙强盛)2 ; Quan, Zhengjun1; Sun W(孙伟)2; Wang, Xicun1; Sun W(孙伟)
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| The second department | 苏州研究院 |
| 2017 | |
| Source Publication | Tetrahedron: Asymmetry
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| ISSN | 0957-4166 |
| Volume | 28Issue:7Pages:954-963 |
| Abstract | A series of chiral tridentate ligands derived from readily available enantiopure L-proline were designed and synthesized. The ligands together with Cu(OAc)2 were successfully used in asymmetric Henry reactions. Various structurally divergent aldehydes and nitromethane were converted into versatile beta-nitro alcohols in MeOH at room temperature with very good yields (up to 85%) and enantioselectivities (up to 86%). |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.tetasy.2017.05.013 |
| Funding Organization | the National Natural Science Foundation of China (21473226;21362031) |
| Indexed By | SCI |
| If | 2.126 |
| Language | 英语 |
| Funding Project | 仿生与生物催化研究组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22441 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） 苏州研究院 |
| Corresponding Author | Wang, Xicun; Sun W(孙伟) |
| Affiliation | 1.College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, and Suzhou Research Center of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China |
| Recommended Citation GB/T 7714 | Xu DQ,Sun QS,Quan, Zhengjun,et al. The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction[J]. Tetrahedron: Asymmetry,2017,28(7):954-963. |
| APA | Xu DQ,Sun QS,Quan, Zhengjun,Sun W,Wang, Xicun,&孙伟.(2017).The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction.Tetrahedron: Asymmetry,28(7),954-963. |
| MLA | Xu DQ,et al."The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction".Tetrahedron: Asymmetry 28.7(2017):954-963. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S095741661730（2579KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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