Ordered mesoporous chromium-zirconium oxophosphate composites with homogeneously dispersed chromium oxide: synthesis, characterization and application in liquid phase oxidation of benzyl alcohol and ethylbenzene | |
Department | OSSO国家重点实验室 |
Miao ZC(苗智超)1; Zhou, Jin1; Li, Zhenbin1; Liu, Dandan1; Zhao, Jinping1; Chou LJ(丑凌军)2; Zhuo, Shuping1; Chou LJ(丑凌军) | |
2017 | |
Source Publication | Journal of Materials Science |
ISSN | 0022-2461 |
Volume | 52Issue:20Pages:12141-12155 |
Abstract | In this paper, a sequence of ordered mesoporous chromium–zirconium oxophosphate (M–Cr–ZrPO) composites with controllable chromium contents (0–15 mol%) were projected and successfully synthesized through a modified one-pot evaporation-induced self-assembly method. Characterized by N2 adsorption–desorption isotherms and TEM techniques, the resultant M–Cr–ZrPO composites owned ordered mesoporous structure and the textural properties [specific surface areas (160–210 m2 g−1), pore volumes (0.25–0.28 cm3 g−1) and pore sizes (5.6–6.6 nm)] of materials were improved by the introduced chromium species. In addition, the dispersion, existing states and contents of introduced chromium species in the materials were researched in detail by elemental mapping images, XRD, UV–vis, FT-IR, XPS and H2-TPR techniques. All the characterizations implied that the chromium oxides were introduced as expected and homogeneously dispersed in the skeleton of mesoporous materials. Owing to the outstanding structural properties and chromium species with homogeneous dispersion, the M–Cr–ZrPO materials exhibited superior catalytic activity for liquid phase oxidation of benzyl alcohol and ethylbenzene. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1007/s10853-017-1387-9 |
Funding Organization | the Natural Science Foundation of China (21373244;21576158;21576159);Shandong Provincial Natural Science Foundation (2015ZRB0176) |
Indexed By | SCI |
If | 2.599 |
Language | 英语 |
Funding Project | 多相催化-1研究组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/22418 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Zhuo, Shuping; Chou LJ(丑凌军) |
Affiliation | 1.Shandong Univ Technol, Sch Chem Engn, Zibo 255049, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Miao ZC,Zhou, Jin,Li, Zhenbin,et al. Ordered mesoporous chromium-zirconium oxophosphate composites with homogeneously dispersed chromium oxide: synthesis, characterization and application in liquid phase oxidation of benzyl alcohol and ethylbenzene[J]. Journal of Materials Science,2017,52(20):12141-12155. |
APA | Miao ZC.,Zhou, Jin.,Li, Zhenbin.,Liu, Dandan.,Zhao, Jinping.,...&丑凌军.(2017).Ordered mesoporous chromium-zirconium oxophosphate composites with homogeneously dispersed chromium oxide: synthesis, characterization and application in liquid phase oxidation of benzyl alcohol and ethylbenzene.Journal of Materials Science,52(20),12141-12155. |
MLA | Miao ZC,et al."Ordered mesoporous chromium-zirconium oxophosphate composites with homogeneously dispersed chromium oxide: synthesis, characterization and application in liquid phase oxidation of benzyl alcohol and ethylbenzene".Journal of Materials Science 52.20(2017):12141-12155. |
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