| Textual properties of Cu-Mn mixed oxides and application for methyl formate synthesis from syngas | |
| Department | ERC国家工程研究中心 |
Zhao HJ(赵海军)1,2 ; Fang, Kegong3; Dong F(董芳)1,2; Lin, Minggui3; Sun, Yuhan4; Tang ZC(唐志诚)1,2; Tang ZC(唐志诚)
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| The second department | osso国家重点实验室 |
| 2017 | |
| Source Publication | Journal of Industrial and Engineering Chemistry
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| ISSN | 1226-086X |
| Volume | 54Pages:117-125 |
| Abstract | Cu-Mn mixed oxides with different calcination temperatures were prepared using ammonia complexing method and evaluated for methyl formate (MF) synthesis from syngas with CaO-ZrO2 as co-catalyst. The influence of calcination temperature on the structure and properties of Cu-Mn mixed oxides was investigated by appropriate characterizations. Cu1.5Mn1.5O4 formed during the calcination of Cu-Mn catalyst at 450 ℃ and played a significant role in the MF synthesis. However, it partially decomposed into CuO and MnO2 when the calcination temperature exceeded 550 ℃. Results showed that the optimum MF selectivity was obtained on Cu-Mn catalyst calcined at 450 ℃, and the highest CO conversion was obtained on the Cu-Mn sample with calcination temperature of 550 ℃. The reaction mechanism of MF synthesis from syngas over Cu-Mn mixed oxides and CaO-ZrO2 co-catalyst was thoroughly studied via typical model reactions, and the nucleophilic addition elimination reaction mechanism was proposed. |
| Keyword | Methyl Formate Cu-mn Mixed Oxides Syngas Methanol Cao-zro2 |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.jiec.2017.05.024 |
| Funding Organization | the National Natural Science Foundation of China (No. 21407154;21507137;21103217;21473230);The National Basic Research Program of China (2013CB933200);the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDA01020304) |
| Indexed By | SCI |
| If | 4.421 |
| Language | 英语 |
| Funding Project | 工业催化研究组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22416 |
| Collection | 精细石油化工中间体国家工程研究中心（ERC） 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Fang, Kegong; Tang ZC(唐志诚) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou 730000, Gansu, Peoples R China 3.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 4.Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201203, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao HJ,Fang, Kegong,Dong F,et al. Textual properties of Cu-Mn mixed oxides and application for methyl formate synthesis from syngas[J]. Journal of Industrial and Engineering Chemistry,2017,54:117-125. |
| APA | Zhao HJ.,Fang, Kegong.,Dong F.,Lin, Minggui.,Sun, Yuhan.,...&唐志诚.(2017).Textual properties of Cu-Mn mixed oxides and application for methyl formate synthesis from syngas.Journal of Industrial and Engineering Chemistry,54,117-125. |
| MLA | Zhao HJ,et al."Textual properties of Cu-Mn mixed oxides and application for methyl formate synthesis from syngas".Journal of Industrial and Engineering Chemistry 54(2017):117-125. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S1226086X1730（2846KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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