Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen
DepartmentERC国家工程研究中心
Wang YG(王圆广)1,2; Meng X(孟旭)1; Chen GX(陈革新)1; Zhao PQ(赵培庆)1; Zhao PQ(赵培庆)
The second department苏州研究院;osso国家重点实验室
2018
Source PublicationCatalysis Communications
ISSN1566-7367
Volume104Issue:0Pages:106-111
Abstract

Copper hydroxide supported on manganese oxide octahedral molecular sieves (Cu(OH)X/OMS-2) was prepared and was found to be highly active for the oxidative cyclization of benzyl alcohols or methylarenes solely with anthranilamides using oxygen as oxidant. The low loading copper hydroxide was used as a catalytic metal. The hydroxyl of catalyst with spherical agglomeration led to higher performance of catalytic activity for the synthesis of quinazolinones. Moreover, Cu(OH)X/OMS-2 could be reused 5 times without any significant loss of activity.

KeywordHeterogeneous Catalysis Green Oxidant Oms-2 Catalytic Oxidation Quinazolinones
Subject Area物理化学与绿色催化
DOI10.1016/j.catcom.2017.10.024
Funding Organizationthe National Natural Science Foundation of China (Grant Nos. 21403256 ; 21573261) ; the Suzhou Industrial Technology and Innovation Project (Grant No. SYG201531)
Indexed BySCI
If3.463
Language英语
Funding Project催化新工艺研究组
compositor第一作者单位
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/22217
Collection精细石油化工中间体国家工程研究中心(ERC)
羰基合成与选择氧化国家重点实验室(OSSO)
苏州研究院
Corresponding AuthorZhao PQ(赵培庆)
Affiliation1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China
2.University of Chinese Academy of Sciences, Beijing 100049, China
Recommended Citation
GB/T 7714
Wang YG,Meng X,Chen GX,et al. Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen[J]. Catalysis Communications,2018,104(0):106-111.
APA Wang YG,Meng X,Chen GX,Zhao PQ,&Zhao PQ.(2018).Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen.Catalysis Communications,104(0),106-111.
MLA Wang YG,et al."Direct synthesis of quinazolinones by heterogeneous Cu(OH)X/OMS-2 catalyst under oxygen".Catalysis Communications 104.0(2018):106-111.
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