| N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates | |
| Department | OSSO国家重点实验室 |
| Jin, Liqun1,2; Hao, Wangfang1; Xu, Jianeng1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Mo WM(莫卫民)1; Hu XQ(胡信全)1,2; Hu XQ(胡信全) | |
| 2017 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 53Issue:29Pages:4124-4127 |
| Abstract | (NHC)-Cu-catalyzed C(sp)–C(sp3) bond formation has been successfully achieved under mild conditions. Nonactivated alkyl triflates, which could be easily derived from alcohols, were utilized as C–O electrophiles. Mechanistic studies suggested that copper acetylide was the active species. Scale-up reactions further demonstrated the practicality and efficiency of the developed strategy. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c7cc00891k |
| Funding Organization | National Natural Science Foundation of China (21603190;21473160;21376224);Jin alsothanks the support from Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province |
| Indexed By | SCI |
| If | 6.319 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/22178 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Jin, Liqun; Hu XQ(胡信全) |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Jin, Liqun,Hao, Wangfang,Xu, Jianeng,et al. N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates[J]. Chemical Communications,2017,53(29):4124-4127. |
| APA | Jin, Liqun.,Hao, Wangfang.,Xu, Jianeng.,Sun N.,Hu BX.,...&胡信全.(2017).N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates.Chemical Communications,53(29),4124-4127. |
| MLA | Jin, Liqun,et al."N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates".Chemical Communications 53.29(2017):4124-4127. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c7cc00891k.pdf（1938KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment