Mutable Properties of Nonheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism | |
Department | OSSO国家重点实验室 |
Kang, Yiran1,2; Li, Xiao-Xi1; Kyung-Bin Cho3; Sun W(孙伟)1; Xia CG(夏春谷)1; Wonwoo Nam1,3; Wang Y(王永)1; Wang Y(王永) | |
2017 | |
Source Publication | Journal of the American Chemical Society |
ISSN | 0002-7863 |
Volume | 139Issue:22Pages:7444-7447 |
Abstract | Although nonheme iron(III)–iodosylarene complexes present amazing oxidative efficiency and selectivity, the nature of such complexes and related oxidation mechanism are still unsolved after decades of experimental efforts. Density functional calculations were employed to explore the structure–reactivity relationship of the iron(III)–iodosylbenzene complex, [FeIII(tpena–) (PhIO)]2+ (1), in thioanisole sulfoxidation. Our theoretical work revealed that complex 1 can evolve into two resonance valence-bond electronic structures (a high-valent iron–oxo species and a monomeric PhIO species) in thioanisole sulfoxidation to present different reaction mechanisms (the novel bond-cleavage coupled electron transfer mechanism or the direct oxygen-atom transfer mechanism) as a response to different substrate attack orientations. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/jacs.7b03310 |
Funding Organization | National Natural Science Foundation of China to Y.W. (grants 21003116;21173211);to W.S. (grant no. 21473226);the NRF of Korea through the CRI (NRF-2012R1A3A2048842);GRL (NRF-2010-00353) to W.N;MSIP (2013R1A1A2062737) to K-B.C. |
Indexed By | SCI |
If | 13.858 |
Language | 英语 |
Funding Project | 仿生与生物催化研究组;均相催化研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21977 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Wonwoo Nam; Wang Y(王永) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea |
Recommended Citation GB/T 7714 | Kang, Yiran,Li, Xiao-Xi,Kyung-Bin Cho,et al. Mutable Properties of Nonheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism[J]. Journal of the American Chemical Society,2017,139(22):7444-7447. |
APA | Kang, Yiran.,Li, Xiao-Xi.,Kyung-Bin Cho.,Sun W.,Xia CG.,...&王永.(2017).Mutable Properties of Nonheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism.Journal of the American Chemical Society,139(22),7444-7447. |
MLA | Kang, Yiran,et al."Mutable Properties of Nonheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism".Journal of the American Chemical Society 139.22(2017):7444-7447. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
jacs.7b03310.pdf(1406KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment