Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides | |
Department | OSSO国家重点实验室 |
Mao, Liuliang1; Li, Yonghong1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
2017 | |
Source Publication | Chinese Journal of Chemistry |
ISSN | 1001-604X |
Volume | 35Issue:3Pages:316-322 |
Abstract | A silver-catalyzed phosphorylation/cyclization radical cascade of 1,6-dienes has been developed. The reaction process involves in a one-pot operation described as an autotandem catalytic process with a cascading radical cyclization for the construction of C—P and C—C bond with high stereoselectivity. Moreover, it also affords an efficient method for the synthesis of valuable exocyclic phosphine oxides compounds with broad substrate applicability, mild reaction condition and succinct reaction system. |
Keyword | Silver-catalyzed Cascade Radical Cyclization Exocyclic Phosphine Oxides 1 6-dienes |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/cjoc.201600707 |
Funding Organization | the NSFC (Nos. 21272100;21472076;21532001);PCSIRT (IRT_15R28;lzujbky-2016-ct02) |
Indexed By | SCI |
If | 1.852 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21617 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Yang SD(杨尚东) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China |
Recommended Citation GB/T 7714 | Mao, Liuliang,Li, Yonghong,Yang SD,et al. Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides[J]. Chinese Journal of Chemistry,2017,35(3):316-322. |
APA | Mao, Liuliang,Li, Yonghong,Yang SD,&杨尚东.(2017).Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides.Chinese Journal of Chemistry,35(3),316-322. |
MLA | Mao, Liuliang,et al."Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides".Chinese Journal of Chemistry 35.3(2017):316-322. |
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Mao_et_al-2017-Chine(416KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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