LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides
DepartmentOSSO国家重点实验室
Mao, Liuliang1; Li, Yonghong1; Yang SD(杨尚东)1,2; Yang SD(杨尚东)
2017
Source PublicationChinese Journal of Chemistry
ISSN1001-604X
Volume35Issue:3Pages:316-322
Abstract

A silver-catalyzed phosphorylation/cyclization radical cascade of 1,6-dienes has been developed. The reaction process involves in a one-pot operation described as an autotandem catalytic process with a cascading radical cyclization for the construction of C—P and C—C bond with high stereoselectivity. Moreover, it also affords an efficient method for the synthesis of valuable exocyclic phosphine oxides compounds with broad substrate applicability, mild reaction condition and succinct reaction system.

KeywordSilver-catalyzed Cascade Radical Cyclization Exocyclic Phosphine Oxides 1 6-dienes
Subject Area物理化学与绿色催化
DOI10.1002/cjoc.201600707
Funding Organizationthe NSFC (Nos. 21272100;21472076;21532001);PCSIRT (IRT_15R28;lzujbky-2016-ct02)
Indexed BySCI
If1.852
Language英语
compositor第二作者单位
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21617
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorYang SD(杨尚东)
Affiliation1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China
Recommended Citation
GB/T 7714
Mao, Liuliang,Li, Yonghong,Yang SD,et al. Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides[J]. Chinese Journal of Chemistry,2017,35(3):316-322.
APA Mao, Liuliang,Li, Yonghong,Yang SD,&杨尚东.(2017).Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides.Chinese Journal of Chemistry,35(3),316-322.
MLA Mao, Liuliang,et al."Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides".Chinese Journal of Chemistry 35.3(2017):316-322.
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