Mechanism of mercury removal by a novel hydrazine hydrate-modified pectin
Department中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
Guo, Jj.1,2; Zhang, Jy.2; Yue Y(岳莹)1; Guo Y(郭勇)1; Guo Y(郭勇)
2014
Source PublicationBulgarian Chemical Communications
ISSN0324-1130
Volume46Issue:4Pages:801-805
Abstract

This paper describes a novel hydrazine hydrate-modified pectin for the removal of Hg2+. The modified pectin was characterized by elemental analysis and FT-IR spectroscopy which indicated that hydrazine hydrate was successfully grafted on the side chains of pectin. In addition, the reaction mechanism between modified pectin and Hg2+ was studied by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results revealed that the removal effect was probably due to the form of the coordination bonds between Hg2+ and N/O atoms. Under optimized experimental conditions, the efficiency of removal Hg2+ by the modified pectin reached 74.8%, which was far higher than the 30.5% obtained with unmodified pectin.

KeywordPectin Modification Mercury Hydrazine Hydrate Mechanism
Subject Area分析化学与药物化学
Funding OrganizationSpecial Plan modern agricultural industry technology system "Waste utilization of potato processing and pollution control" of Gansu Province (nycytx-15)
Indexed BySCI
If0.201
Language英语
Funding Project药物分离材料研究组
compositor第一作者单位
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/21253
Collection中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室
Corresponding AuthorGuo Y(郭勇)
Affiliation1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Chem Northwestern Plant Resources, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China
2.Lanzhou Univ Technol, Coll Petro Chem Engn, Lanzhou 730050, Peoples R China
Recommended Citation
GB/T 7714
Guo, Jj.,Zhang, Jy.,Yue Y,et al. Mechanism of mercury removal by a novel hydrazine hydrate-modified pectin[J]. Bulgarian Chemical Communications,2014,46(4):801-805.
APA Guo, Jj.,Zhang, Jy.,Yue Y,Guo Y,&郭勇.(2014).Mechanism of mercury removal by a novel hydrazine hydrate-modified pectin.Bulgarian Chemical Communications,46(4),801-805.
MLA Guo, Jj.,et al."Mechanism of mercury removal by a novel hydrazine hydrate-modified pectin".Bulgarian Chemical Communications 46.4(2014):801-805.
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