Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex | |
Department | OSSO国家重点实验室 |
Shen DY(沈都益)1; Claudio Saracini1; Yong-Min Lee1; Sun W(孙伟)2; Shunichi Fukuzumi1,3; Wonwoo Nam1,2; Sun W(孙伟) | |
2016 | |
Source Publication | Journal of the American Chemical Society |
ISSN | 0002-7863 |
Volume | 138Issue:49Pages:15857-15860 |
Abstract | Photocatalytic enantioselective epoxidation of terminal olefins using a mononuclear non-heme chiral manganese catalyst, [(R,R-BQCN)MnII]2+, and water as an oxygen source yields epoxides with relatively high enantioselectivities (e.g., up to 60% enantiomeric excess). A synthetic mononuclear non-heme chiral Mn(IV)–oxo complex, [(R,R-BQCN)MnIV(O)]2+, affords similar enantioselectivities in the epoxidation of terminal olefins under stoichiometric reaction conditions. Mechanistic details of each individual step of the photoinduced catalysis, including formation of the Mn(IV)–oxo intermediate, are discussed on the basis of combined results of laser flash photolysis and other spectroscopic methods. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1021/jacs.6b10836 |
Funding Organization | the NRF of Korea through the CRI (NRF-2012R1A3A2048842 to W.N.);GRL (NRF-2010-00353 to W.N.) Programs;JSPS KAKENHI (16H02268 to S.F.);the National Natural Science Foundation of China (21473226 to S.W.);the National Research Foundation of Korea (Grant NRF-2015H1D3A1066507) |
Indexed By | SCI |
If | 13.858 |
Language | 英语 |
Funding Project | 生物与仿生催化课题组 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/21209 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Shunichi Fukuzumi; Wonwoo Nam; Sun W(孙伟) |
Affiliation | 1.Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Meijo Univ, Japan Sci & Technol Agcy JST, SENTAN, Fac Sci & Engn, Nagoya, Aichi 4688502, Japan |
Recommended Citation GB/T 7714 | Shen DY,Claudio Saracini,Yong-Min Lee,et al. Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex[J]. Journal of the American Chemical Society,2016,138(49):15857-15860. |
APA | Shen DY.,Claudio Saracini.,Yong-Min Lee.,Sun W.,Shunichi Fukuzumi.,...&孙伟.(2016).Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex.Journal of the American Chemical Society,138(49),15857-15860. |
MLA | Shen DY,et al."Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex".Journal of the American Chemical Society 138.49(2016):15857-15860. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
jacs.6b10836.pdf(824KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment