A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions | |
Department | OSSO国家重点实验室 |
Xu, Jian-Xing1; Ye, Fei1; Bai XF(柏惺峰)1,2; Cui, Yu-Ming1; Xu, Zheng1; Zheng ZJ(郑战江)1; Xu LW(徐利文)1,2; Xu LW(徐利文) | |
2016 | |
Source Publication | RSC Advances |
ISSN | 2046-2069 |
Volume | 6Issue:74Pages:70624-70631 |
Abstract | To shield light on the mechanism of palladium-catalyzed allylic substitutions with structurally diverse nucleophiles (up to 99% ee) in the presence of Fei-Phos ligand (chiral trans-1,2-diaminocyclohexane-derived biphosphine, CycloN2P2-Phos) as an effective chiral P-ligand, mechanistic studies were performed for clarification of the role of multifunctional Fei-Phos in this reaction. The cooperative action of nitrogen and phosphorous atoms in the present Pd-catalyzed allylic alkylation is proved to be a diphosphine-based catalyst system but not a nitrogen-controlled or monophosphine-involved transition state. |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1039/c6ra15665g |
Funding Organization | the National Natural Science Foundation of China (No. 21173064;51303043;21472031;21503060);Zhejiang Provincial Natural Science Foundation of China (LR14B030001) |
Indexed By | SCI |
If | 3.108 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/20683 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Xu LW(徐利文) |
Affiliation | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Xu, Jian-Xing,Ye, Fei,Bai XF,et al. A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions[J]. RSC Advances,2016,6(74):70624-70631. |
APA | Xu, Jian-Xing.,Ye, Fei.,Bai XF.,Cui, Yu-Ming.,Xu, Zheng.,...&徐利文.(2016).A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions.RSC Advances,6(74),70624-70631. |
MLA | Xu, Jian-Xing,et al."A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions".RSC Advances 6.74(2016):70624-70631. |
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c6ra15665g.pdf(1883KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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