Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones

doi:10.1039/c6ob00505e

	Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones
Department	固体润滑国家重点实验室
	Zhou, Zhao-Zhao 1; Zheng, Lan 1; Yan, Xiao-Biao 1; Jin, Dong-Po 1; He, Yu-Tao 1; Liang YM(梁永民)1,2; Liang YM(梁永民)
	2016
Source Publication	Organic and Biomolecular Chemistry
ISSN	1477-0520
Volume	14 Issue:19 Pages:4507-4510
Abstract	A silver-promoted oxidative cascade cyclization with a phosphorylation/1,5-aryl migration/desulfonylation/dearomatization process is presented here, providing an efficient method to synthesize azaspiro[4.5]decenones with high regioselectivity. The cinnamamidyl radical, which has rarely been reported before, plays a key role in this reaction.
Subject Area	材料科学与物理化学
DOI	10.1039/c6ob00505e
Funding Organization	the National Natural Science Foundation (NSF 21272101;21472073);the "111" Project (J1103307);Program for Changjiang Scholars and Innovative Research Team in University (IRT1138)
Indexed By	SCI
If	3.564
Language	英语
compositor	第二作者单位
Citation statistics	Cited Times:22[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/20105
Collection	固体润滑国家重点实验室（LSL）
Corresponding Author	Liang YM(梁永民)
Affiliation	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
Recommended Citation GB/T 7714	Zhou, Zhao-Zhao,Zheng, Lan,Yan, Xiao-Biao,et al. Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones[J]. Organic and Biomolecular Chemistry,2016,14(19):4507-4510.
APA	Zhou, Zhao-Zhao.,Zheng, Lan.,Yan, Xiao-Biao.,Jin, Dong-Po.,He, Yu-Tao.,...&梁永民.(2016).Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones.Organic and Biomolecular Chemistry,14(19),4507-4510.
MLA	Zhou, Zhao-Zhao,et al."Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones".Organic and Biomolecular Chemistry 14.19(2016):4507-4510.

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