| Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES | |
| Department | OSSO国家重点实验室 |
| Li F(李菲)1; Zhou, Wei1; Zheng LS(郑龙生)1; Li L(李莉)1; Zheng ZJ(郑战江)1; Xu LW(徐利文)1,2; Xu LW(徐利文) | |
| 2014 | |
| Source Publication | Synthetic Communications
 |
| ISSN | 0039-7911 |
| Volume | 44Issue:19Pages:2861-2869 |
| Abstract | In this work, we have developed a facile protocol with salan–Cu system for the facile and selective synthesis of β-hydroxyesters via silyl-Reformatsky reaction with α-silylester and aldehydes. The screening and optimization of reaction conditions led to the determination of a practical and efficient procedure in which the salan–Cu exhibited promising catalytic activity in dimethylsulfoxide, in which the silyl-Reformatsky reaction of aromatic aldehydes with α-trimethylsilylmethylacetate gave the corresponding β-hydroxyester derivatives in excellent yields (up to 98%) under fluoride-free reaction conditions. |
| Keyword | Ar-binmol Aromatic Aldehydes Organosilicon Chemistry Reformatsky Reaction Salan Ligand |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1080/00397911.2014.920509 |
| Funding Organization | the National Natural Science Founder of China (No. 21173064;51303043);Zhejiang Provincial Natural Science Foundation of China (LR14B030001;LQ12B02004);Program for Excellent Young Teachers in Hangzhou Nornal University (HNUEYT, JTAS 2011-01-04) |
| Indexed By | SCI |
| If | 0.929 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19270 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xu LW(徐利文) |
| Affiliation | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Coll Mat Chem & Chem Engn, Minist Educ, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Li F,Zhou, Wei,Zheng LS,et al. Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES[J]. Synthetic Communications,2014,44(19):2861-2869. |
| APA | Li F.,Zhou, Wei.,Zheng LS.,Li L.,Zheng ZJ.,...&徐利文.(2014).Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES.Synthetic Communications,44(19),2861-2869. |
| MLA | Li F,et al."Ar-BINMOL-DERIVED SALAN-Cu(II) COMPLEX-CATALYZED SILYL-REFORMATSKY REACTION OF AROMATIC ALDEHYDES".Synthetic Communications 44.19(2014):2861-2869. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| SynthCommun2014v44n1（739KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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