| Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates | |
| Department | OSSO国家重点实验室 |
Zhao YW(赵应伟) ; Xie YJ(谢银君); Xia CG(夏春谷); Huang HM(黄汉民); Xia CG(夏春谷); Huang HM(黄汉民)
| |
| 2014 | |
| Source Publication | Advanced Synthesis and Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 356Issue:11-12Pages:2471-2476 |
| Abstract | A palladium-catalyzed intramolecular C-H bond sulfuration reaction of aryl thiocarbamates has been developed. This strategy provides a new route to benzo[d][1,3] oxathiol-2-ones with tolerance of a wide range of substituents. Mechanistic studies suggested that the C-H activation-sulfuration to afford 2-imino-1,3-benzoxathiole intermediate might involve an electrophilic palladation process. |
| Keyword | C-h Activation Benzo[d][1 Palladium 3]Oxathiol-2-ones Sulfuration Thiocarbamates |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201400306 |
| Funding Organization | the National Natural Science Foundation of China (21203222;21133011;21173241) |
| Indexed By | SCI |
| If | 5.663 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19256 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Huang HM(黄汉民) |
| Affiliation | Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao YW,Xie YJ,Xia CG,et al. Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates[J]. Advanced Synthesis and Catalysis,2014,356(11-12):2471-2476. |
| APA | Zhao YW,Xie YJ,Xia CG,Huang HM,夏春谷,&黄汉民.(2014).Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates.Advanced Synthesis and Catalysis,356(11-12),2471-2476. |
| MLA | Zhao YW,et al."Palladium-Catalyzed Intramolecular Oxidative C-H Sulfuration of Aryl Thiocarbamates".Advanced Synthesis and Catalysis 356.11-12(2014):2471-2476. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01028446.pdf（391KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment