| Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions | |
| Department | 绿色化学研究发展中心 |
Ke ZG(柯振刚)1,2 ; Zhang Y(张妍)1; Cui XJ(崔新江)1; Shi F(石峰)1; Shi F(石峰)
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| The second department | osso国家重点实验室 |
| 2016 | |
| Source Publication | Green Chemistry
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| ISSN | 1463-9262 |
| Volume | 18Issue:3Pages:808-816 |
| Abstract | A simple and efficient Au/Al2O3 catalyst was prepared by the co-precipitation method for the oxidative N-formylation of amines with paraformaldehyde. Under the optimized reaction conditions, excellent amine conversion and N-formamide selectivity can be obtained with up to 97% yield with water as the solvent under ambient conditions. This catalyst tolerated a wide range of primary amines and second amines, and it can be reused for at least five runs without obvious deactivation. |
| Keyword | N-formylation Paraformaldehyde Au/al2o3 Catalyst |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c5gc01992c |
| Funding Organization | the National Natural Science Foundation of China (21203219);Youth Innovation Promotion Association CAS |
| Indexed By | SCI |
| If | 9.125 |
| Language | 英语 |
| Funding Project | 纳米催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/19042 |
| Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Shi F(石峰) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Ke ZG,Zhang Y,Cui XJ,et al. Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions[J]. Green Chemistry,2016,18(3):808-816. |
| APA | Ke ZG,Zhang Y,Cui XJ,Shi F,&石峰.(2016).Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions.Green Chemistry,18(3),808-816. |
| MLA | Ke ZG,et al."Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions".Green Chemistry 18.3(2016):808-816. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Green.pdf（1513KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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