| Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains | |
| Department | OSSO国家重点实验室 |
Wu B(吴彪)1; Huo, Cuirong1; Li SG(李少光)2; Zhao YX(赵艳霞)1; Yang XJ(杨晓娟)1 ; Wu B(吴彪)
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| 2015 | |
| Source Publication | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
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| ISSN | 0044-2313 |
| Volume | 641Issue:10Pages:1786-1791 |
| Abstract | A series of alkanediyl-spaced bis-bisurea ligands (L2–L4) were synthesized and their anion coordination behavior studied. These ligands form interesting complexes with polymeric and oligomeric dihydrogen phosphate aggregates in the solid state. The ligands L2 and L3 coordinate with H2PO4– anions to form a unique molecular “necklace” with an infinite (H2PO4–)n chain and surrounding ligand molecules. Meanwhile, two different dihydrogen phosphate-water oligomers, (H2PO4)6·(H2O)4 and (H2PO4)4·(H2O)2, were observed in the complexes with the ligands L3 and L4. In addition, solution anion binding properties of the ligands were studied by 1H NMR and UV/Vis spectroscopy. |
| Keyword | Oligourea Dihydrogen Phosphate Anion Clusters Anion Coordination Nmr Spectroscopy Uv Vis Spectroscopy |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/zaac.201500243 |
| Funding Organization | the National Natural Science Foundation of China (21271149;21325102) |
| Indexed By | SCI |
| If | 1.160 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18557 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Wu B(吴彪) |
| Affiliation | 1.NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Wu B,Huo, Cuirong,Li SG,et al. Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(10):1786-1791. |
| APA | Wu B,Huo, Cuirong,Li SG,Zhao YX,Yang XJ,&吴彪.(2015).Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(10),1786-1791. |
| MLA | Wu B,et al."Anion Coordination of Bis-bisurea Ligands: Aggregation of Dihydrogen Phosphate Anion into Oligomers and Infinite Chains".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.10(2015):1786-1791. |
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| File Name/Size | DocType | Version | Access | License | ||
| Wu_et_al-2015-Zeitsc（624KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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