LICP OpenIR  > 羰基合成与选择氧化国家重点实验室(OSSO)
Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed CX Bond Cleavage to Environmentally Benign Transition-Metal-Free CH Bond Activation
DepartmentOSSO国家重点实验室
Xu, Zheng1; Xu LW(徐利文)1,2; Xu LW(徐利文)
2015
Source PublicationChemSusChem
ISSN1864-5631
Volume8Issue:13Pages:2176-2179
Abstract

The construction of carbon–silicon bonds is highlighted as an exciting achievement in the field of organosilicon chemistry and green chemistry. Recent developments in this area will enable the sustainable chemical conversion of silicon resources into synthetically useful compounds. Especially, the catalytic silylation through C[BOND]H bond activation without directing groups and hydrogen acceptors is one of the most challenging topics in organic chemistry and green chemistry. These remarkable findings on catalytic silylation can pave the way to a more environmentally benign utilization of earth-abundant silicon-based resources in synthetic chemistry.

KeywordC-h Activation Green Chemistry Homogeneous Catalysis Silicon Synthetic Methods
Subject Area物理化学与绿色催化
DOI10.1002/cssc.201500467
Funding Organizationthe National Natural Science Foundation of China (No. 21173064;21472031);Fundamental Research Funds for the Central Universities (GK201501005);Zhejiang Provincial Natural Science Foundation of China (LR14B030001)
Indexed BySCI
If7.657
Language英语
compositor第二作者单位
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18493
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Corresponding AuthorXu LW(徐利文)
Affiliation1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Xu, Zheng,Xu LW,Xu LW. Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed CX Bond Cleavage to Environmentally Benign Transition-Metal-Free CH Bond Activation[J]. ChemSusChem,2015,8(13):2176-2179.
APA Xu, Zheng,Xu LW,&徐利文.(2015).Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed CX Bond Cleavage to Environmentally Benign Transition-Metal-Free CH Bond Activation.ChemSusChem,8(13),2176-2179.
MLA Xu, Zheng,et al."Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed CX Bond Cleavage to Environmentally Benign Transition-Metal-Free CH Bond Activation".ChemSusChem 8.13(2015):2176-2179.
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