| Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway | |
| Department | OSSO国家重点实验室 |
| Shen ZL(沈振陆)1; Chen, Meng1; Fang, Tiantian2; Li, Meichao1; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Sun N(孙楠)1; Hu XQ(胡信全)1,3; Shen ZL(沈振陆); Hu XQ(胡信全) | |
| 2015 | |
| Source Publication | Tetrahedron Letters
 |
| ISSN | 0040-4039 |
| Volume | 56Issue:21Pages:2768-2772 |
| Abstract | A facile and efficient protocol for direct transformation of p-methoxybenzyl (PMB) ethers to aldehydes or ketones via a catalytic aerobic oxidation process has been developed. The reaction was performed with the combination of catalytic amounts of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,2,6,6-tetramethylpiperidine N-oxy (TEMPO), and tert-butyl nitrite (TBN), with molecular oxygen as terminal oxidant. A variety of PMB ether substrates derived from benzylic alcohols, heteroaromatic alcohols, and aliphatic alcohols, were converted to their corresponding carbonyl compounds in good conversions and selectivities. |
| Keyword | Functional Group Interconversion Pmb Ethers Carbonyl Compounds Oxidation Oxygen |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.tetlet.2015.04.033 |
| Funding Organization | the National Natural Science Foundation of China (21376224;21206147);Opening Foundation of Zhejiang Key Course of Chemical Engineering and Technology, Zhejiang University of Technology (20130211) |
| Indexed By | SCI |
| If | 2.379 |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18444 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Shen ZL(沈振陆); Hu XQ(胡信全) |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 2.Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Shen ZL,Chen, Meng,Fang, Tiantian,et al. Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway[J]. Tetrahedron Letters,2015,56(21):2768-2772. |
| APA | Shen ZL.,Chen, Meng.,Fang, Tiantian.,Li, Meichao.,Mo WM.,...&胡信全.(2015).Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway.Tetrahedron Letters,56(21),2768-2772. |
| MLA | Shen ZL,et al."Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway".Tetrahedron Letters 56.21(2015):2768-2772. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 20152768-2772.pdf（3986KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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