Asymmetric Suzuki-Miyaura Cross-Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands | |
Department | OSSO国家重点实验室 |
Ma YN(马艳娜)1; Yang SD(杨尚东)1,2 | |
2015 | |
Source Publication | Chemistry - A European Journal |
ISSN | 0947-6539 |
Volume | 21Issue:18Pages:6673-6677 |
Abstract | Efficient asymmetric Suzuki-Miyaura coupling reactions have been employed for the first time to synthesize chiral biaryl compounds with phosphinate groups as chiral auxiliaries. A series of functionalized chiral biaryls are thereby synthesized in excellent yields and good diastereoselectivities (up to > 95: 5 d.r.) and axially chiral monophosphorus ligands are obtained through further functionalizations. |
Keyword | Asymmetric Synthesis Biaryl Compounds Cross-coupling Ligand Design Phosphanes |
DOI | 10.1002/chem.201406554 |
Funding Organization | the NSFC (Nos. 21272100;21472076);the Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT: IRT1138);the Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07) |
Indexed By | SCI |
If | 5.771 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18431 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 73000, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Ma YN,Yang SD. Asymmetric Suzuki-Miyaura Cross-Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands[J]. Chemistry - A European Journal,2015,21(18):6673-6677. |
APA | Ma YN,&Yang SD.(2015).Asymmetric Suzuki-Miyaura Cross-Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands.Chemistry - A European Journal,21(18),6673-6677. |
MLA | Ma YN,et al."Asymmetric Suzuki-Miyaura Cross-Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands".Chemistry - A European Journal 21.18(2015):6673-6677. |
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Ma_et_al-2015-Chemis(518KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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