Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines | |
Department | OSSO国家重点实验室 |
Zhang GY(张国营); Gao B(高宝); Huang HM(黄汉民); Huang HM(黄汉民) | |
2015 | |
Source Publication | Angewandte Chemie International Edition |
ISSN | 1433-7851 |
Volume | 54Issue:26Pages:7657-7661 |
Abstract | A novel and efficient palladium-catalyzed hydroaminocarbonylation of alkenes with aminals has been developed under mild reaction conditions, and allows the synthesis of a wide range of N-alkyl linear amides in good yields with high regioselectivity. On the basis of this method, a cooperative catalytic system operating by the synergistic combination of palladium, paraformaldehyde, and acid was established for promoting the hydroaminocarbonylation of alkenes with both aromatic and aliphatic amines, which do not react well under conventional palladium-catalyzed hydroaminocarbonylation. |
Keyword | Alkenes Amines Aminals Palladium Synthetic Methods |
Subject Area | 物理化学与绿色催化 |
DOI | 10.1002/anie.201502405 |
Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21172226;21133011) |
Indexed By | SCI |
If | 11.709 |
Language | 英语 |
Funding Project | 有机功能材料研究组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18329 |
Collection | 羰基合成与选择氧化国家重点实验室(OSSO) |
Corresponding Author | Huang HM(黄汉民) |
Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
Recommended Citation GB/T 7714 | Zhang GY,Gao B,Huang HM,et al. Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines[J]. Angewandte Chemie International Edition,2015,54(26):7657-7661. |
APA | Zhang GY,Gao B,Huang HM,&黄汉民.(2015).Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines.Angewandte Chemie International Edition,54(26),7657-7661. |
MLA | Zhang GY,et al."Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome the Basicity Barrier Imparted by Aliphatic Amines".Angewandte Chemie International Edition 54.26(2015):7657-7661. |
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Zhang_et_al-2015-Ang(683KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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