| Synthesis of carbon nitride powder by selective etching of TiC0.3N0.7 in chlorine-containing atmosphere at moderate temperature | |
| Department | 固体润滑国家重点实验室 ; 先进润滑与防护材料研究发展中心 |
Sui J(眭剑); Lv JJ(吕晋军)
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| 2010 | |
| Source Publication | Materials Chemistry and Physics
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| ISSN | 0254-0584 |
| Volume | 123Pages:264-268 |
| Abstract | We reported the synthesis of carbon nitride powder by extracting titanium from single inorganic pre-cursor TiC0.3N0.7 in chlorine-containing atmosphere at ambient pressure and temperature not exceeding500 ◦C. The TiC0.3N0.7 crystalline structure acted as a template, supplying active carbon and nitrogenatoms for carbon nitride when it was destroyed in chlorination. X-ray diffraction data showed that theobtained carbon nitride powders were amorphous, which was in good agreement with transmissionelectron microscope analysis. The composition and structure of carbon nitride powders were analyzedby employing Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray photoelectronspectroscopy. Results indicated that disorder structure was most likely for the carbon nitride powdersand the N content depended greatly on the chlorination temperature. Thermal analysis in flowing N2indicated that the mass loss started from 300 ◦C and the complete decomposition occurred at around650 ◦C, confirming the low thermal stability of the carbon nitride material. |
| Keyword | Nitride Etching Fourier Transform Infrared Spectroscopy (Ftir) X-ray Photo-emission Spectroscopy (Xps) |
| Subject Area | 材料科学与物理化学 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 金属基高温润滑材料组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1038 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Lv JJ(吕晋军) |
| Recommended Citation GB/T 7714 | Sui J,Lv JJ. Synthesis of carbon nitride powder by selective etching of TiC0.3N0.7 in chlorine-containing atmosphere at moderate temperature[J]. Materials Chemistry and Physics,2010,123:264-268. |
| APA | 眭剑,&吕晋军.(2010).Synthesis of carbon nitride powder by selective etching of TiC0.3N0.7 in chlorine-containing atmosphere at moderate temperature.Materials Chemistry and Physics,123,264-268. |
| MLA | 眭剑,et al."Synthesis of carbon nitride powder by selective etching of TiC0.3N0.7 in chlorine-containing atmosphere at moderate temperature".Materials Chemistry and Physics 123(2010):264-268. |
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| 2010264-268.pdf（880KB） | 开放获取 | License | View Application Full Text | |||
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