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Template-Free and Direct Electrochemical Deposition of Hierarchical Dendritic Gold Microstructures: Growth and Their Multiple Applications
Department固体润滑国家重点实验室
Ye WC(叶为春); Yan JF(严俊峰); Ye Q(叶谦); Zhou F(周峰)
2010
Source PublicationJournal of Physical Chemistry C
ISSN1932-7447
Volume114Issue:37Pages:15617-15624
AbstractHierarchical dendritic gold microstrutures (HDGMs) with secondary and tertiary branches are directlyelectrodeposited on an indium tin oxide (ITO) substrate without the use of any templates, surfactants, orstabilizers. The effects of electrodeposition potential and HAuCl4 concentration on the formation of HDGMsand time-dependent morphological evolution are investigated in detail. A diffusion-limited aggregation (DLA)mechanism is used to explain the formation of HDGMs. Typically, the as-synthesized HDGMs exhibitedmuch higher electrocatalytic activity and enhanced stability toward ethanol electrooxidation compared tobulk gold electrode and also display great Raman enhancement activity with the detection limit of 10 12Mfor rhodamine 6G. The surface of HDGMs possesses hydrophobicity even without modification with low-surface-energy coatings and has a remarkable superhydrophobic property even in corrosive solutions over awide pH range after the treatment with n-dodecanethiol. In addition, (super)oleophobicity is successfullyobtained by modification with 1H,1H,2H,2H-perfluorodecanethiol.
Subject Area材料科学与物理化学
Funding Organizationthe “Hundred Talents Program” of the Chinese Academy of Sciences;the NSFC(50835009, 20973188)
Indexed BySCI
Language英语
Funding Project材料表面与界面行为研究组
Citation statistics
Cited Times:165[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/1022
Collection固体润滑国家重点实验室(LSL)
Corresponding AuthorZhou F(周峰)
Recommended Citation
GB/T 7714
Ye WC,Yan JF,Ye Q,et al. Template-Free and Direct Electrochemical Deposition of Hierarchical Dendritic Gold Microstructures: Growth and Their Multiple Applications[J]. Journal of Physical Chemistry C,2010,114(37):15617-15624.
APA 叶为春,严俊峰,叶谦,&周峰.(2010).Template-Free and Direct Electrochemical Deposition of Hierarchical Dendritic Gold Microstructures: Growth and Their Multiple Applications.Journal of Physical Chemistry C,114(37),15617-15624.
MLA 叶为春,et al."Template-Free and Direct Electrochemical Deposition of Hierarchical Dendritic Gold Microstructures: Growth and Their Multiple Applications".Journal of Physical Chemistry C 114.37(2010):15617-15624.
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