Preparation and characterization of patterned copper sulfide thin films on n-type TiO2 film surfaces | |
Department | 固体润滑国家重点实验室 |
Lu YJ(卢永娟); Yi GW(易戈文); Jia JH(贾均红); Liang YM(梁永民) | |
2010 | |
Source Publication | Applied Surface Science |
ISSN | 0169-4332 |
Volume | 256Pages:7316-7322 |
Abstract | Micro-arrayed patterns of p-type copper sulfide (CuxS) thin filmswith positive and negative featuresweredeposited onto the surfaces of n-type TiO2 semiconductor films via a selective nucleation and growthprocess from aqueous solution. The surface functional molecules of the UV photo-oxidised patternedSAMs were utilized to direct the nucleation and growth of CuxS crystallites. The resultant CuxS/TiO2composite films with negative and positive CuxS patterns on the TiO2 film surface were investigatedusing SEM, XRD, XPS and a 3D Surface Profiler. It is demonstrated that regular and compact patternedfilms of Cu2S crystallites had been deposited onto the n-type TiO2 surface,with sharp edges demarcatingthe boundaries between the patterned Cu2S region and the TiO2 film region. The UV–vis spectra forthree Cu2S/TiO2 films exhibit awide absorption between 300 nmand 450 nm. Themaximumwavelengthdifferences in the spectra of Cu2S/TiO2 films and TiO2 filmwere attributed to the added absorption of Cu2Sfilms at 302 nm and the unchanged adsorption of TiO2 films. The absorption intensities of the Cu2S/TiO2films could be varied in the UV–vis range using the Cu2S patterned features (positive, negative). |
Keyword | Copper Sulfide Thin FIlm Micropattern Characterization Optical Property |
Subject Area | 材料科学与物理化学 |
Funding Organization | the National Science Foundation of China (Grant # 50705094);the “Hundred Talents Program” of Chinese Academy of Sciences (Grant # KGCX2- YW-804);SRF for ROCS-SEM for providing the financial support |
Indexed By | SCI |
Language | 英语 |
Funding Project | 高温抗磨材料组 |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/952 |
Collection | 固体润滑国家重点实验室(LSL) 中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心 |
Corresponding Author | Jia JH(贾均红) |
Recommended Citation GB/T 7714 | Lu YJ,Yi GW,Jia JH,et al. Preparation and characterization of patterned copper sulfide thin films on n-type TiO2 film surfaces[J]. Applied Surface Science,2010,256:7316-7322. |
APA | 卢永娟,易戈文,贾均红,&梁永民.(2010).Preparation and characterization of patterned copper sulfide thin films on n-type TiO2 film surfaces.Applied Surface Science,256,7316-7322. |
MLA | 卢永娟,et al."Preparation and characterization of patterned copper sulfide thin films on n-type TiO2 film surfaces".Applied Surface Science 256(2010):7316-7322. |
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